Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Tracking transformation processes of organic micropollutants in aquatic environments using multi-element isotope fractionation analysis
Date
2011-06-01
Author
Hofstetter, Thomas B.
Bolotin, Jakov
Skarpeli-Liati, Marita
Wijker, Reto
Kurt, Zöhre
Nishino, Shirley F.
Spain, Jim C.
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
255
views
0
downloads
Cite This
The quantitative description of enzymatic or abiotic transformations of man-made organic micropollutants in rivers, lakes, and groundwaters is one of the major challenges associated with the risk assessment of water resource contamination. Compound-specific isotope analysis enables one to identify (bio)degradation pathways based on changes in the contaminants' stable isotope ratios even if multiple reactive and non-reactive processes cause concentrations to decrease. Here, we investigated how the magnitude and variability of isotope fractionation in some priority pollutants is determined by the kinetics and mechanisms of important enzymatic and abiotic redox reactions. For nitroaromatic compounds and substituted anilines, we illustrate that competing transformation pathways can be assessed via trends of N and C isotope signatures.
Subject Keywords
Geochemistry and Petrology
,
Pollution
,
Environmental Chemistry
URI
https://hdl.handle.net/11511/42781
Journal
APPLIED GEOCHEMISTRY
DOI
https://doi.org/10.1016/j.apgeochem.2011.03.068
Collections
Department of Environmental Engineering, Article
Suggestions
OpenMETU
Core
Assessment of PCB contamination, the potential for in situ microbial dechlorination and natural attenuation in an urban watershed at the East Coast of the United States
Kaya, Devrim; Sowers, Kevin R.; Demirtepe, Hale; Stiell, Brian; Baker, Joel E.; İmamoğlu, İpek; Kjellerup, Birthe (Elsevier BV, 2019-09-15)
Sediment contamination is a major environmental issue in many urban watersheds and coastal areas due to the potential toxic effects of contaminants on biota and human health. Characterizing and delineating areas of sediment contamination and toxicity are important goals of coastal resource management in terms of ecological and economical perspectives. Core and surficial sediment samples were collected from an industrialized urban watershed at the East Coast of the United Stated and analyzed to evaluate the ...
An Assessment of the Spatial Distribution of Polychlorinated Biphenyl Contamination in Turkey
Gedik, Kadir; İmamoğlu, İpek (Wiley, 2010-02-01)
This study summarizes the relevant information regarding the spatial distribution of polychlorinated biphenyls (PCBs) in various environmental (e.g., soil, sediment, air, water) and biological (e.g., fish, mussel, adipose tissue, milk) media in Turkey. The information sources, used for this purpose, in addition to the scientific literature, were; official import records, governmental reports on monitoring of organochlorines, and reports prepared by international organizations. PCBs were never produced in Tu...
Modeling natural attenuation of petroleum hydrocarbons (btex) in heterogeneous aquifers
Uçankuş, Tuğba; Ünlü, Kahraman; Department of Environmental Engineering (2005)
Natural Attenuation can be an effective cleanup option for remediation of Groundwater contamination by BTEX. One of the important aspects of the methodology that has been recognized recently is that mass removal rates, the most important parameters used to determine effectiveness of the methodology, is controlled by groundwater flow regime, which to a large extent controlled by aquifer heterogeneity. Considering this recognition, the primary objective of this research is to quantitatively describe the relat...
The effects of aquifer heterogeneity on the natural attenuation rates of chlorinated solvents
Önkal, Başak; Ünlü, Kahraman; Department of Environmental Engineering (2005)
Monitored natural attenuation has been particularly used at sites where petroleum hydrocarbons and chlorinated solvents have contaminated soil and groundwater. One of the important aspects of the methodology that has been recognized recently is that the mass removal rates, the most important parameter to determine effectiveness of the methodology, is controlled by the groundwater flow regime and the aquifer heterogeneity. Considering this recognition, the primary objective of this study is to quantitatively...
Evaluation of PCB dechlorination pathways in anaerobic sediment microcosms using an anaerobic dechlorination model
Demirtepe, Hale; Kjellerup, Birthe; Sowers, Kevin R.; İmamoğlu, İpek (Elsevier BV, 2015-10-15)
A detailed quantitative analysis of anaerobic dechlorination (AD) pathways of polychlorinated biphenyls (PCBs) in sediment microcosms was performed by applying an anaerobic dechlorination model (ADM). The purpose of ADM is to systematically analyze changes in a contaminant profile that result from microbial reductive dechlorination according to empirically determined dechlorination pathways. In contrast to prior studies that utilized modeling tools to predict dechlorination pathways, ADM also provides quant...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
T. B. Hofstetter et al., “Tracking transformation processes of organic micropollutants in aquatic environments using multi-element isotope fractionation analysis,”
APPLIED GEOCHEMISTRY
, pp. 0–0, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/42781.