A bio-sensing platform utilizing a conjugated polymer, carbon nanotubes and PAMAM combination

Date

2017-08-15

Author

Buber, Ece
Kesik, Melis
Soylemez, Saniye
Toppare, Levent Kamil

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In this study, amperometric biosensing performance of a novel platform utilizing a conducting polymer (CP), multi-walled carbon nanotubes (MWCNTs) and poly(amidoamine) (PAMAM) dendrimer was constructed. In order to fabricate the proposed biosensor, a graphite electrode was modified with poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with N,N-bis(4-methylphenyl)-4-aniline (PFLA), MWCNTs and PAMAM, respectively. Then, GOx was immobilized onto the modified surface with the help of glutaraldehyde (GA) as the crosslinking reagent. Then, analytical and kinetic parameters of the constructed biosensor were investigated and the biosensor showed a linear response for glucose between 0.05 and 0.75 mM with a detection limit of 0.014 mM. K-M(app) and sensitivity values were calculated as 0.66 mM and 55.41 mu A mM(-1) cm(-2), respectively. To investigate the surface modifications, scanning electron microscopy (SEM) and cyclic voltammetry (CV) techniques were used. Finally, fabricated biosensor was tested on beverages for glucose detection successfully.

Subject Keywords

Analytical Chemistry, Electrochemistry, General Chemical Engineering

URI

https://hdl.handle.net/11511/43889

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY

DOI

https://doi.org/10.1016/j.jelechem.2017.06.043

Collections

Department of Chemistry, Article

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Citation Formats

E. Buber, M. Kesik, S. Soylemez, and L. K. Toppare, “A bio-sensing platform utilizing a conjugated polymer, carbon nanotubes and PAMAM combination,” JOURNAL OF ELECTROANALYTICAL CHEMISTRY, pp. 370–376, 2017, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/43889.