Synthesis and Optoelectronic Properties of Iptycene-Naphthazarin Dyes

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2019-01-01

Author

Dengiz, Çağatay
SWAGER, Timothy M.

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We report the synthesis and characterization of iptycene-naphthazarin dyes by using a sequential Diels-Alder approach. The tautomerization of naphthazarin was used as the key step in the synthesis, with structures confirmed by single-crystal X-ray and NMR analysis. The systematic trends in electronic properties were investigated by UV/Vis spectroscopy BF2 complexes of the dyes were prepared by reaction with BF3 OEt2 in CH2Cl2.

Subject Keywords

Naphthazarin, Iptycenes, Diels-Alder, Tautomerization, Epimerization

URI

https://hdl.handle.net/11511/45141

Journal

SYNLETT

DOI

https://doi.org/10.1055/s-0037-1611169

Collections

Department of Chemistry, Article

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Citation Formats

Ç. Dengiz and T. M. SWAGER, “Synthesis and Optoelectronic Properties of Iptycene-Naphthazarin Dyes,” SYNLETT, pp. 54–58, 2019, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/45141.