Borophosphates: Hydrothermal and microwave-assisted synthesis of Na-5[B2P3O13]

Date

1998-10-01

Author

Hauf, C
Yılmaz, Ayşen
Kizilyalli, M
Kniep, R

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Na-5[B2P3O13] was first prepared by high temperature synthesis (T-max = 780 degrees C) and was characterized by X-ray single crystal investigations recently. We have now succeeded in the hydrothermal synthesis of the compound and obtained single-phase products at 150 degrees C after 1-2 days. A microwave-assisted synthesis takes only 2 min to transform a solid mixture of berate and phosphate hydrates into the crystalline title compound. Pure Na-5[B2P3O13] melts at 747 degrees C and solidifies during cooling by formation of a homogeneous glass. (C) 1998 academic Press.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Materials Chemistry, Electronic, Optical and Magnetic Materials, Condensed Matter Physics, Ceramics and Composites

URI

https://hdl.handle.net/11511/47891

Journal

JOURNAL OF SOLID STATE CHEMISTRY

DOI

https://doi.org/10.1006/jssc.1998.7955

Collections

Department of Chemistry, Article

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Citation Formats

C. Hauf, A. Yılmaz, M. Kizilyalli, and R. Kniep, “Borophosphates: Hydrothermal and microwave-assisted synthesis of Na-5[B2P3O13],” JOURNAL OF SOLID STATE CHEMISTRY, pp. 154–156, 1998, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/47891.