Characterization of Particulate Matter Emitted from Combustion of Various Biomasses in O-2/N-2 and O-2/CO2 Environments

Date

2014-01-01

Author

Ruscio, Amanda
Kazanç Özerinç, Feyza
Levendis, Yiannis A.

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

149
views

0
downloads

This work reports on the physical and chemical characteristics of the ashes of biomass residues burned in air as well as in simulated dry oxy-combustion conditions. Three pulverized biomass residues (olive residue, corn residue, and torrefied pine sawdust) were burned in a laboratory-scale laminar-flow drop tube furnace heated to 1400 K. Olive residue resulted in by far the largest particulate yields both submicrometer (PM1) and supermicrometer (PM1-18)-whereas torrefied pine sawdust resulted in the lowest. The collected particulate yields of these two biomasses were analogous to their ash contents. The collected particulate yields of corn residue, however, were lower than expected in view of its ash content. To investigate the effects of the oxygen mole fraction and of the background gas, the O-2 mole fraction was varied from 20% to 60% in either N-2 or CO2. Submicrometer particulate matter (PM1) emission yields of all three fuels were lower in O-2/CO2 than in O-2/N-2 environments; they typically, but not always, increased with increasing O-2 mole fraction in either background gas. The background gas had little effect on the chemical composition of the PM1 particles. High amounts of alkalis (potassium, calcium, and sodium) as well as of. chlorine were observed in PM1. In addition, phosphorus and sulfur also existed in high amounts in PM1 from combustion of corn residue. Supermicrometer particles (PM1-18) yields exhibited no clear trend when the background gas was changed or when the oxygen mole fraction was increased. The composition of these particles reflected the bulk ash composition of the parent fuels.

Subject Keywords

Fuel Technology, Energy Engineering and Power Technology, General Chemical Engineering

URI

https://hdl.handle.net/11511/48808

Journal

ENERGY & FUELS

DOI

https://doi.org/10.1021/ef401796w

Collections

Department of Mechanical Engineering, Article

Suggestions

OpenMETU
Core

Characterization and kinetics of light crude oil combustion in the presence of metallic salts Kök, Mustafa Verşan (American Chemical Society (ACS), 2004-05-01) In this research, a reaction cell, thermogravimetry (TG), and differential thermal analysis (DTA) were used to characterize the light crude oil combustion and kinetics in the presence of copper(I) chloride (CuCl) and magnesium chloride (MgCl2·6H2O). In TG-DTA experiments with magnesium chloride, three reaction regions were identified, known as distillation, low-temperature oxidation (LTO), and high-temperature oxidation (HTO). In the case of copper(I) chloride, two main transitional stages are observed with...
Characterization of lignocellulose biomass and model compounds by thermogravimetry Kök, Mustafa Verşan (Informa UK Limited, 2017-01-01) In this research, combustion characteristics of lignocellulose biomass (hazelnut shell) and three main components (cellulose, hemicellulose, and lignin) were investigated using thermogravimetry (TGA-DTG) technique at different heating rates. The ignition, peak, burn-out temperatures, and the heat liberation of lignocellulose biomass and three main components were also measured. Two different model-free kinetic methods, known as Ozawa-Flynn-Wall (OFW) and Kissinger-Akahira-Sunose (KAS), were used in order to...
PREDICTION OF BED MATERIAL ACTIVITY FROM CHANGES IN CARBON-DIOXIDE CONCENTRATION FOLLOWING COAL PARTICLE INJECTION IN THE FLUIDIZED-BED REACTOR VURAL, H (Elsevier BV, 1994-01-01) An electrically heated laboratory scale fluidized bed reactor was used for measurement of carbon dioxide concentrations from the devolatilization of bituminous coal under conditions pertinent to a large scale atmospheric pressure fluidized bed combustor (AFBC). Feeding a few particles into the bed, which contained 1 or 2 g of char, produced an increase in CO2 concentration. The quantity of CO2 released from the fluidized bed was found to be a function of fluidizing solid material, as well as the bed tempera...
Effects of operational parameters and ultrasonic pretreatment on supercritical CO2 extraction of diesel fuel from soil Guvenc, A; Mehmetoglu, U; Mehmetoglu, T (Informa UK Limited, 2004-01-01) Supercritical fluid extraction (SFE) using CO2 was performed on soil material artificially contaminated with diesel fuel. Raising the temperature from 313 K to 343 K caused the recovery efficiency to increase from 52 to 76%. Pressure and CO2 flow rate were found to be less important. As expected, increasing extraction time resulted in higher recoveries. Ultrasonic pretreatment of the soil material was found to be very effective, possibly due to disrupting the strong interaction bonding between soil matrix a...
Analytical investigation of wet combustion process for heavy oil recovery Bağcı, Ali Suat (Informa UK Limited, 2004-12-01) Analysis of combustion tube data produced from experiments performed under realistic reservoir conditions is currently the most valid method of investigating in-situ combustion process. In this study, the optimization of water-air ratio for B. Kozluca heavy crude oil, and the comparison of the performance of dry and wet forward combustion processes were studied. An analytical model was used to extend the laboratory results so that the oil production and steam zone volume can be estimated under field conditi...

Citation Formats

A. Ruscio, F. Kazanç Özerinç, and Y. A. Levendis, “Characterization of Particulate Matter Emitted from Combustion of Various Biomasses in O-2/N-2 and O-2/CO2 Environments,” ENERGY & FUELS, pp. 685–696, 2014, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48808.