Dual-type electrochromic devices based on conducting copolymers of thiophene-functionalized monomers

Date

2005-01-03

Author

BULUT, U
Çırpan, Ali

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Dual polymer electrochromic devices (ECDs) composed of electrochemically deposited conducting copolymers of thiophene-functionalized monomers, 2-[(3-thienylcarbonyl)oxy] ethyl 3-thiophene carboxylate (TOET), 2,3-bis-[(3-thienylcarbonyl)oxy]propyl 3-thiophene carboxylate (TOPT), and 3-[(3-thienylcarbonyl)oxy]-2,2-bis-[(3-thienylcarbonyl)oxy]propyl 3-thiophene carboxylate (TOTPT), and polyethylene dioxythiophene (PEDOT) as the counter part were constructed with tetrabutylammonium tetrafluoroborate (TBAFB) doped gelled poly(methyl methacrylate) (PMMA) and evaluated. An electrochromic device with the following configuration was assembled - indium tin oxide (ITO)-coated glass /conducting copolymer parallel to gel electrolyte parallel to PEDOT/ITO. Spectroelectrochemistry, electrochromic switching, stability and open-circuit memory of the devices were examined.

Subject Keywords

Mechanical Engineering, Materials Chemistry, Mechanics of Materials, Electronic, Optical and Magnetic Materials, Condensed Matter Physics, Metals and Alloys

URI

https://hdl.handle.net/11511/49185

Journal

SYNTHETIC METALS

DOI

https://doi.org/10.1016/j.synthmet.2004.07.008

Collections

Department of Chemistry, Article

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Citation Formats

U. BULUT and A. Çırpan, “Dual-type electrochromic devices based on conducting copolymers of thiophene-functionalized monomers,” SYNTHETIC METALS, pp. 65–69, 2005, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/49185.