Microporous patterned electrodes for color-matched electrochromic polymer displays

Date

2004-06-15

Author

Aubert, Pierre-Henri
ARGUN, Avni A.
Çırpan, Ali
TANNER, David B.
REYNOLDS, John R.

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

172
views

0
downloads

The emergence of electroactive and conducting polymers offers new opportunities for the design of materials for electrochromic devices (ECDs). Of these, poly(3,4-alkylenedioxythiophene)s (PXDOTs) and their derivatives exhibit the most promising electrochromic (EC) properties. Here, we report the use of highly porous metallized membranes which allow the production of patterned, rapid-switching, reflective ECDs. Using poly(3,4-ethylenedioxithiophene) (PEDOT), poly(3.,4-propylenedioxythiophene) (PProDOT), and the dimethyl-substituted derivative PProDOT-Me-2 as the active EC materials, we have obtained switching times of 0.1-0.2 s (5-10 Hz) to achieve full EC contrast. These polymers yield reflective contrast values of up to 90% in the NIR and similar to60% in the visible regions. In addition, the ECDs were switched repetitively, 180 000 times with less than 10% contrast loss. We have also demonstrated a 2 x 2 pixelated display device built using shadow mask patterning. Two cathodically coloring polymers which exhibit two distinct colors in their neutral states (blue and red) are patterned on a porous metallized electrode to yield a highly contrasted surface. Upon simultaneous oxidation of these polymers, the bi-color surface is rapidly bleached presenting a uniform shiny gold surface.

Subject Keywords

Materials Chemistry, General Chemistry, General Chemical Engineering

URI

https://hdl.handle.net/11511/49223

Journal

Chemistry of Materials

DOI

https://doi.org/10.1021/cm049951s

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

Flexible organic photovoltaics from zinc oxide nanowires grown on transparent and conducting single walled carbon nanotube thin films Ünalan, Hüsnü Emrah; Kuo, Daniel; Parekh, Bhavin; Amaratunga, Gehan; Chhowalla, Manish (Royal Society of Chemistry (RSC), 2008-01-01) The fabrication of flexible organic photovoltaics (OPVs) which utilize transparent and conducting single walled carbon nanotube (SWNT) thin films as current collecting electrodes on plastic substrates in zinc oxide nanowire (ZnO NW)/poly(3-hexylthiophene) (P3HT) bulk heterojunction photovoltaic devices is reported. The bulk heterojunctions for exciton dissociation are created by directly growing ZnO nanowires from solution on the SWNT electrodes and spin coating the P3HT polymer. A maximum OPV power convers...
Spray processable ambipolar benzotriazole bearing electrochromic polymers with multi-colored and transmissive states Hizalan, Goenuel; Balan, Abidin; Baran, Derya; Toppare, Levent Kamil (Royal Society of Chemistry (RSC), 2011-01-01) In the context of low cost flexible display device technology, requirements can be fulfilled with accessible multi-colored electrochromic polymers. Here, we report the synthesis and electrochromic properties of two spray processable, ambipolar, fluorescent and multi-color to transmissive electrochromic polymers. Polymers, PTBTPh and PTBTTh, have multi-colored oxidation states and easily accessible n-doped states, which allowed us to achieve transmissive films in a low working potential. Electrochemical and ...
Electrochromic and photovoltaic applications of benzotriazole bearing donor acceptor type conjugated polymers Baran, Derya; Toppare, Levent Kamil; Department of Chemistry (2010) Organic semi-conductors are of great interest since these compounds can be utilized as active layers in many device applications such as ECDs, LEDs and solar cells. Incorporating the benzotriazole units into the polymer backbone enhances the optical properties of donor units. Hexyl thiophene and pyrrole are commonly used as electron donor materials. Benzotriazole can be coupled to hexyl thiophene or pyrrole to yield materials which can be polymerized to give donor acceptor type polymers. These materials are...
New, highly stable electrochromic polymers from 3,4-ethylenedioxythiophene-bis-substituted quinoxalines toward green polymeric materials Durmus, Asuman; Günbaş, Emrullah Görkem; Toppare, Levent Kamil (American Chemical Society (ACS), 2007-12-11) Two new highly stable electrochromic polymers, poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,3-di(thiophen-2-yl)quinoxaline) (PDETQ) and poly (5,8-bis(2,3 -dihydrothieno[3,4-b][ 1,4]dioxin-5yl)quinoxaline) (PDEQ) were synthesized, and their potential use as neutral state green polymeric materials was investigated. Spectroelectrochemistry showed that both polymers reveal two distinct absorption bands as expected for this type of donor-acceptor polymer, at 410 and 660 nm for PDEQ and 405 and 780 nm...
A bio-sensing platform utilizing a conjugated polymer, carbon nanotubes and PAMAM combination Buber, Ece; Kesik, Melis; Soylemez, Saniye; Toppare, Levent Kamil (Elsevier BV, 2017-08-15) In this study, amperometric biosensing performance of a novel platform utilizing a conducting polymer (CP), multi-walled carbon nanotubes (MWCNTs) and poly(amidoamine) (PAMAM) dendrimer was constructed. In order to fabricate the proposed biosensor, a graphite electrode was modified with poly[9,9-di-(2-ethylhexyl)-fluorenyl-2,7-diyl] end capped with N,N-bis(4-methylphenyl)-4-aniline (PFLA), MWCNTs and PAMAM, respectively. Then, GOx was immobilized onto the modified surface with the help of glutaraldehyde (GA...

Citation Formats

P.-H. Aubert, A. A. ARGUN, A. Çırpan, D. B. TANNER, and J. R. REYNOLDS, “Microporous patterned electrodes for color-matched electrochromic polymer displays,” Chemistry of Materials, pp. 2386–2393, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/49223.