THE MILD N-NITROSATION OF SECONDARY-AMINES WITH TRICHLORONITROMETHANE

Date

1992-01-01

Author

Demir, Ayhan Sıtkı
MAHASNEH, AS
AKSOY, H
GERCEK, Z

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

42
views

0
downloads

Reaction of trichloronitromethane with secondary amine leads to the formation

Subject Keywords

Organic Chemistry

URI

https://hdl.handle.net/11511/51347

Journal

SYNTHETIC COMMUNICATIONS

DOI

https://doi.org/10.1080/00397919208021659

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

THE ALPHA'-OXIDATION OF ALPHA-ALKOXY ENONES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS Demir, Ayhan Sıtkı; SAATCIOGLU, A (Informa UK Limited, 1993-01-01) The alpha'-oxidation of cyclic derivatives of alpha-alkoxy-alpha,beta-unsaturated ketones using manganese(III)acetate in the presence of various carboxylic acids provided a convenient synthesis of 5-acyloxy-2-alkoxy-2-cyclopentenones and 6-acyloxy-2-alkoxy-2-cyclohexenones.
Unusual fragmentation of fulvene endoperoxides with phenyliodosyl bis(trifluoroacetate) (PIFA) Ozer, G; Saracoglu, N; Balcı, Metin (Wiley, 2003-05-01) Reaction of unsaturated fulvene endoperoxides with dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate gave saturated fulvene endoperoxides containing the 1,2-dihydropyridazine ring. Treatment of dihydropyridazine endoperoxides with water followed by phenyliodosyl bis(trifluoroacetate) oxidation provided acrylic acid derivatives and dimethyl pyridazine-3,6-dicarboxylate.
A facile synthesis of various butenolides Tanyeli, Cihangir (Informa UK Limited, 2000-01-01) The synthesis of alpha'-acyloxy-alpha,beta-unsaturated cyclic ketones from the corresponding alpha,beta-unsaturated cyclic ketones by using manganese (III) acetate in combination with 2-chloropropionic acid followed by subsequent Arbuzov and intramolecular Horner-Emmons cyclization reactions provided a convenient synthetic pathway to various butenolides 4a-d.
One-pot synthesis of chloroalcohols and their lipase mediated kinetic resolution - ferrocenyl aziridinylmethanols as chiral ligands in enantioselective conjugate diethylzinc addition to enones İşleyen, Alper; Doğan, Özdemir; Department of Chemistry (2007) An unexpected tricyclic ether formation instead of acetate addition to the double bond of a norbornene derivative aroused our interest to explore the mechanism of this reaction. Mechanistic studies showed that methylene diacetate (MDA) was formed in the stock solution (NBu4OAc + dichloromethane) and decomposed to formaldehyde under Lewis or Brønsted acid conditions. Formaldehyde and olefin condensation (Prins reaction) clearly explains the formation of the unexpected product. Same methodology was then succe...
Oxidation of Primary Alcohols to Aldehydes with N-Halamine-Containing Polymers Akdağ, Akın; Öztürk, Perihan (Georg Thieme Verlag KG, 2013-11-12) Polymeric N-halamines have been previously employed for organic reactions such as sulfide oxidation. In the present study, we employed polymeric N-halamines to oxidize primary alcohols selectively to the corresponding aldehydes in excellent yields. After reaction, the polymers can be recycled and then reused for the next reaction process.

Citation Formats

A. S. Demir, A. MAHASNEH, H. AKSOY, and Z. GERCEK, “THE MILD N-NITROSATION OF SECONDARY-AMINES WITH TRICHLORONITROMETHANE,” SYNTHETIC COMMUNICATIONS, pp. 2607–2611, 1992, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51347.