Reaction of cycloheptatriene derivatives with 1,3-diketones in the presence of Mn(OAc)(3)

Date

2011-01-01

Author

Sudemen, Mahir Burak
ZENGİN, MUSTAFA
GENÇ, HAYRİYE
Balcı, Metin

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The reactions of some 1,3-dicarbonyl compounds with cycloheptatriene derivatives in the presence of Mn(OAc)(3) were examined. Cycloheptatriene forms mainly [2+3] and [6+3] dihydrofuran addition products derived from cycloheptatriene. However, the reaction of acetylacetone with cycloheptatriene substituted with an electron withdrawing group exclusively gave products derived from the norcaradiene structure. The formation mechanism of the products as well as the role of the substituent attached to cycloheptatriene is discussed.

Subject Keywords

Cycloheptatriene, Norcaradiene, Manganese(III) acetate, 1,3-dicarbonyl compounds, Radicals

URI

https://hdl.handle.net/11511/51591

Journal

TURKISH JOURNAL OF CHEMISTRY

DOI

https://doi.org/10.3906/kim-1011-776

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

M. B. Sudemen, M. ZENGİN, H. GENÇ, and M. Balcı, “Reaction of cycloheptatriene derivatives with 1,3-diketones in the presence of Mn(OAc)(3),” TURKISH JOURNAL OF CHEMISTRY, pp. 1–11, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51591.