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Synthesis of beta-chloro-alpha-aminophosphonate derivatives via the regioselective ring opening of unactivated aziridine-2-phosphonates
Date
2018-12-02
Author
Polat-Cakir, Sidika
BEKSULTANOVA, Nurzhan
Doğan, Özdemir
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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A series of unactivated racemic and chiral aziridine-2-phosphonates were synthesized by modified Gabriel-Cromwell reaction. Ring opening reaction of the synthesized phosphonates by gaseous HCl provided access to a wide range of biologically interesting novel beta-chloro-alpha-aminophosphonates. All reactions toward each of the above-mentioned products can be conducted regioselectively in high yields.
Subject Keywords
Inorganic Chemistry
,
Organic Chemistry
,
Biochemistry
URI
https://hdl.handle.net/11511/46586
Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
DOI
https://doi.org/10.1080/10426507.2018.1513521
Collections
Department of Chemistry, Article