Chloroacetonylation of C=C double bonds promoted by manganese(III) acetate

Date

2012-02-01

Author

Dengiz, Çağatay
BALCI, METİN

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The addition of acetylacetone to alkenes was performed using Mn(OAc)(3 center dot)2H(2)O in the presence of HCl. The intermediate formed was trapped by chloride. Removal of one of the acetyl groups with ammonia under very mild conditions provided compounds derived from chloroacetonylation of the double bonds.

Subject Keywords

Acetylacetone, Manganese(III) acetate, Cyclization, Chloroacetonylation, Dihydrofuran

URI

https://hdl.handle.net/11511/35777

Journal

TETRAHEDRON LETTERS

DOI

https://doi.org/10.1016/j.tetlet.2011.11.098

Collections

Department of Chemistry, Article

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Citation Formats

Ç. Dengiz and M. BALCI, “Chloroacetonylation of C=C double bonds promoted by manganese(III) acetate,” TETRAHEDRON LETTERS, pp. 550–552, 2012, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35777.