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Dipole moments of some styrene copolymers
Date
1988-7
Author
Küçükyavuz, Zühal
Baysal, Bahattin
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Dipolemomentsofpoly(styrene-co-p-chlorostyrene),poly(styrene-co-p-methoxystyrene),poly(styrene-co-4-vinylpyridine),andpoly(styrene-co-N-vinylcarbazole)copolymersweredeterminedintoluenesolutionsatdifferenttemperatures.Thesamplesweresynthesizedbyusingfree-radicalinitiators.Theeffectsofthenatureofthepolargroup,composition,andtemperatureonthedipolemomentratiowereinvestigated.Themean-squaredipolemomentperstructuralunitshowsapositivedeviationfromlinearity,inagreementwithcalculationsbyMarkbasedonrotationalisomericstatetheory.Theresultsarecomparedwithotherexperimentalandtheoreticalstudies.
Subject Keywords
Inorganic Chemistry
,
Organic Chemistry
,
Materials Chemistry
,
Polymers and Plastics
URI
https://hdl.handle.net/11511/51918
Journal
Macromolecules
DOI
https://doi.org/10.1021/ma00185a070
Collections
Department of Chemistry, Article