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Dipole moments of some styrene copolymers
Date
1988-7
Author
Küçükyavuz, Zühal
Baysal, Bahattin
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Dipolemomentsofpoly(styrene-co-p-chlorostyrene),poly(styrene-co-p-methoxystyrene),poly(styrene-co-4-vinylpyridine),andpoly(styrene-co-N-vinylcarbazole)copolymersweredeterminedintoluenesolutionsatdifferenttemperatures.Thesamplesweresynthesizedbyusingfree-radicalinitiators.Theeffectsofthenatureofthepolargroup,composition,andtemperatureonthedipolemomentratiowereinvestigated.Themean-squaredipolemomentperstructuralunitshowsapositivedeviationfromlinearity,inagreementwithcalculationsbyMarkbasedonrotationalisomericstatetheory.Theresultsarecomparedwithotherexperimentalandtheoreticalstudies.
Subject Keywords
Inorganic Chemistry
,
Organic Chemistry
,
Materials Chemistry
,
Polymers and Plastics
URI
https://hdl.handle.net/11511/51918
Journal
Macromolecules
DOI
https://doi.org/10.1021/ma00185a070
Collections
Department of Chemistry, Article
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Z. Küçükyavuz and B. Baysal, “Dipole moments of some styrene copolymers,”
Macromolecules
, pp. 2287–2291, 1988, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51918.