Dipole moments of some styrene copolymers

Date

1988-7

Author

Küçükyavuz, Zühal
Baysal, Bahattin

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Dipolemomentsofpoly(styrene-co-p-chlorostyrene),poly(styrene-co-p-methoxystyrene),poly(styrene-co-4-vinylpyridine),andpoly(styrene-co-N-vinylcarbazole)copolymersweredeterminedintoluenesolutionsatdifferenttemperatures.Thesamplesweresynthesizedbyusingfree-radicalinitiators.Theeffectsofthenatureofthepolargroup,composition,andtemperatureonthedipolemomentratiowereinvestigated.Themean-squaredipolemomentperstructuralunitshowsapositivedeviationfromlinearity,inagreementwithcalculationsbyMarkbasedonrotationalisomericstatetheory.Theresultsarecomparedwithotherexperimentalandtheoreticalstudies.

Subject Keywords

Inorganic Chemistry, Organic Chemistry, Materials Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/51918

Journal

Macromolecules

DOI

https://doi.org/10.1021/ma00185a070

Collections

Department of Chemistry, Article

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Citation Formats

Z. Küçükyavuz and B. Baysal, “Dipole moments of some styrene copolymers,” Macromolecules, pp. 2287–2291, 1988, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51918.