CONDUCTIVE PROPERTIES OF POLY(4-VINYLPYRIDINE) POLY(DIMETHYLSILOXANE) BLOCK-COPOLYMERS DOPED WITH TETRACYANOQUINODIMETHANE

Date

1993-01-01

Author

NUGAY, N
KUCUKYAVUZ, Z
KUCUKYAVUZ, S

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Poly(4-vinylpyridine)-poly(dimethylsiloxane) (P4VP-PDMS) block copolymers with various compositions were prepared by anionic polymerization. The 4VP block was quaternized with methyl iodide and reacted with 7,7',8,8'-tetracyanoquinodimethane (TCNQ), which is in both anion radical (TCNQ-.) and neutral form (TCNQ0). The products were then characterized by H-1 nuclear magnetic resonance and Fourier-transform infra-red spectroscopy, scanning electron microscopy and differential scanning calorimetry techniques. The electrical conductivities of processable and flexible films of these block copolymers were measured with the four-probe method and found to be as high as 10(-2) S cm-1. The optimal TCNQ0 doping for which the conductivities are highest were also determined.

Subject Keywords

Organic Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/67053

Journal

POLYMER

DOI

https://doi.org/10.1016/0032-3861(93)90697-9

Collections

Department of Chemistry, Article

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Citation Formats

N. NUGAY, Z. KUCUKYAVUZ, and S. KUCUKYAVUZ, “CONDUCTIVE PROPERTIES OF POLY(4-VINYLPYRIDINE) POLY(DIMETHYLSILOXANE) BLOCK-COPOLYMERS DOPED WITH TETRACYANOQUINODIMETHANE,” POLYMER, pp. 4649–4654, 1993, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/67053.