Calculation of Magnetization and Magnetic Susceptibility Close to Magnetic Phase Transitions in (CH3)2NH2FeIIINiII(HCOO)6 and (CH3)2NH2FeIIICuII(HCOO)6

2020-01-01
We study the temperature and magnetic field dependence of the magnetization (M) and the inverse susceptibility (chi(-1)) in the metal-organic frameworks, in particular, for (CH3)(2)(NH2FeNiII)-Ni-III(HCOO)(6) (DMFeNi) and (CH3)(2)(NH2FeCuII)-Cu-III(HCOO)(6) (DMFeCu) close to their magnetic phase transitions. The Landau phenomenological model is employed to analyze the experimental data for the M(T, H) from the literature and to calculate chi(-1)(T, H) of DMFeNi and DMFeCu. Our results indicate that the thermodynamic model studied explains adequately the observed behavior of M(T, H) for DMFeNi and DMFeCu, which exhibit a weakly first-order (or nearly second order) magnetic phase transition.
Journal of Low Temperature Physics

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Citation Formats
H. H. Yurtseven, “Calculation of Magnetization and Magnetic Susceptibility Close to Magnetic Phase Transitions in (CH3)2NH2FeIIINiII(HCOO)6 and (CH3)2NH2FeIIICuII(HCOO)6,” Journal of Low Temperature Physics, pp. 0–0, 2020, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/52222.