Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products

Date

2001-08-01

Author

Akdağ, Akın
Turker, L

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Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid was carried out. The products were characterized. The experimental results were compared with the theoretical ones which was based on AM1 (UHF) type semi-empirical calculations. The theoretical results disfavor any mechanism solely based on radical stability involving radicals originating from the reactants.

Subject Keywords

Manganese(III) acetate, Oxidation, Enones, Ketones, AM1 calculations

URI

https://hdl.handle.net/11511/52383

Journal

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM

DOI

https://doi.org/10.1016/s0166-1280(01)00567-x

Collections

Department of Chemistry, Article

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Citation Formats

A. Akdağ and L. Turker, “Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products,” JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, pp. 201–206, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/52383.