Partitioning of trace elements during fluidized bed combustion of high ash content lignite

2005-05-25
Selçuk, Nevin
Gogebakan, Zuhal
The behavior of 20 trace elements (As, B, Ba, Cd, Co, Cr, Cu, Hg, Li, Mn, Mo, Ni, P, Pb, Sb, Se, Sn, Tl, V, Zn) and 8 major and minor elements (Al, Ca, Fe, K, Mg, Na, Si, Ti) during the combustion of high ash content lignite with and without limestone addition have been investigated in the 0.3 MWt Middle East Technical University (METU) Atmospheric Bubbling Fluidized Bed Combustor (ABFBC) Test Rig. Experiments were performed without fines recycle. Inert bed material utilized in the experiments was bed ash obtained previously from the combustion of the same lignite without limestone addition in the same test rig. Concentrations of trace elements in coal, limestone, bottom ash, cyclone ash and filter ash were determined by Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). Measurements show that the distribution of major and minor elements follows the ash split between the bottom ash and fly ash and that the major proportion of most of the trace elements (As, Ba, Cr, Hg, Li, Mo, Ni, Sn, V, Zn) are recovered in fly ash. Comparisons between the trace element partitioning of the runs with and without limestone addition reveal that addition of limestone shifts the partitioning of Ba, Cr, Hg, Mo, Ni, Sn, V, Zn from bottom ash to fly ash.

Suggestions

Partitioning behavior of trace elements during pilot-scale fluidized bed combustion of high ash content lignite
Selçuk, Nevin; Gogebakan, Zuhal (2006-10-11)
This study describes the partitioning of 20 trace elements (As, B, Ba, Cd, Co, Cr, Cu, Hg, Li, Mn, Mo, Ni, P, Pb, Sb, Se, Sn, TI, V, Zn) and eight major and minor elements (Al, Ca, Fe, K, Mg, Na, Si, Ti) during the combustion of high ash content lignite. The experiments were carried out in the 0.3 MW, Middle East Technical University (METU) atmospheric bubbling fluidized bed combustor (ABFBC) test rig with and without limestone addition. Inert bed material utilized in the experiments was bed ash obtained pr...
Trace elements partitioning during co-firing biomass with lignite in a pilot-scale fluidized bed combustor
Gogebakan, Zuhal; Selçuk, Nevin (2009-03-15)
This study describes the partitioning of 18 trace elements (As, Ba, Cd, Co, Cr, Cu, Li, Mn, Mo, Ni, P, Pb, Sb, Se, Sn, Tl, V, Zn) and 9 major and minor elements (Al, Ca, Fe, K, Mg, Na, S, Si, Ti) during co-firing of olive residue, hazelnut shell and cotton residue with high sulfur and ash content lignite in 0.3 MWt Middle East Technical University (METU) Atmospheric Bubbling Fluidized Bed Combustor (ABFBC) test rig with limestone addition. Concentrations of trace elements in coal, biomass, limestone, bottom...
Determination of metal concentrations in lichen samples by inductively coupled plasma atomic emission spectroscopy technique after applying different digestion procedures
Tuncel, Süleyman Gürdal; Dogangun, A (2004-05-28)
Three digestion procedures have been tested on lichen samples for application in the determination of major, minor and trace elements (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Ph, V and Zn) in lichen samples collected in Aegean Region of Turkey by inductively coupled plasma atomic emission spectrometer (ICP-AES). The acid mixture of concentrated HNO3, H2O2 and HF were used. The instrument was optimized using lichen matrix considering RF power, nebulizer pressure, auxiliary flow rate and Pump rate. The acc...
TRACE-METAL CHARACTERIZATION OF AIRBORNE PARTICLES FROM THE NORTHEASTERN MEDITERRANEAN
KUBILAY, N; YEMENICIOGLU, S; SAYDAM, C (1994-07-01)
Data from 24 airborne dust samples collected on a land-based atmospheric collection tower at the southeastern coast of Turkey and analyzed for Al, Fe, Mn, Cr, Ni, V, Co, Na, Ca, Mg, Zn, Pb and Cd are presented.
Trace element and major ion composition of wet and dry depositon in Ankara Turkey
Kaya, Güven; Tuncel, Süleyman Gürdal (1997-12-01)
Daily, wet-only precipitation samples collected over a two year period were analyzed for SO42-, NO3-, Cl-, NH4+, H+, Ca, Mg, K, Na, Al, Cu, Cd, Cr, Zn, V and Ni. Weekly dry-deposition samples collected on petri-dishes over the same period were analyzed only for major ions. Concentrations of ions and elements in Ankara precipitation are comparable with concentrations reported in literature for other urban areas. However, the wet deposition fluxes are the lowest among literature values, owing to small annual ...
Citation Formats
N. Selçuk and Z. Gogebakan, “Partitioning of trace elements during fluidized bed combustion of high ash content lignite,” 2005, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/54365.