An unprecedented Co-II-tetraphenylporphyrin-catalyzed decomposition of bicyclic endoperoxides: A new approach to substituted furofuran systems

Date

2000-04-01

Author

Sengul, ME
Simsek, N
Balcı, Metin

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Co-II-tetraphenylporphyrin-catalyzed decomposition of bicyclic endoperoxides 4 and 5 with a strained double bond moiety has been studied. Compounds 4 and 5 have been synthesized by photooxygenation of 3 which itself was obtained by dichloroketene addition to cycloheptatriene, followed by removal of the chlorine atoms. An unusual decomposition mode of 4 promoted by Co-II-TPP resulted in the formation of 8 and 9 which are important building blocks in furofuran systems.

Subject Keywords

Endoperoxides, Cycloheptatriene, Dichloroketene, Singlet oxygen, Cobalt, Porphyrins, Furofurans

URI

https://hdl.handle.net/11511/55372

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

M. Sengul, N. Simsek, and M. Balcı, “An unprecedented Co-II-tetraphenylporphyrin-catalyzed decomposition of bicyclic endoperoxides: A new approach to substituted furofuran systems,” EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, pp. 1359–1363, 2000, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55372.