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Trapping of unsaturated fulvene endoperoxides with dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate: A new synthesis of alkylidene- and arylidenemalonaldehydes
Date
2000-04-01
Author
Ozer, G
Saracoglu, N
Balcı, Metin
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Unsaturated fulvene endoperoxides (2a-e) were trapped with dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate (4). The formed saturated fulvene endoperoxides containig 1,2-dihydropyridazine ring (6a-e) were characterised by spectroscopic methods. Treatment of (6a-e) with cobalt(II) tetraphenylporphyrin (CoTPP) provided alkylidene- and arylidenemalonaldehydes (9a-e).
Subject Keywords
Cobalt(II) tetraphenylporphyrine
,
Singlet oxygen
,
Cycloaddition reaction
URI
https://hdl.handle.net/11511/55761
Journal
HETEROCYCLES
Collections
Graduate School of Natural and Applied Sciences, Article
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G. Ozer, N. Saracoglu, and M. Balcı, “Trapping of unsaturated fulvene endoperoxides with dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate: A new synthesis of alkylidene- and arylidenemalonaldehydes,”
HETEROCYCLES
, pp. 761–764, 2000, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55761.