The facile synthesis of cyclopentanoid antibiotic kjellmanianone

Date

1996-01-01

Author

Demir, Ayhan Sıtkı
Tanyeli, Cihangir
Gulbeyaz, V
Akgul, H

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The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate beta-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.

Subject Keywords

MANGANESE(III) ACETATE, CARBOXYLIC-ACIDS, COMBINATION, OXIDATION, ENONES

URI

https://hdl.handle.net/11511/55921

Journal

TURKISH JOURNAL OF CHEMISTRY

Collections

Department of Chemistry, Article

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Citation Formats

A. S. Demir, C. Tanyeli, V. Gulbeyaz, and H. Akgul, “The facile synthesis of cyclopentanoid antibiotic kjellmanianone,” TURKISH JOURNAL OF CHEMISTRY, pp. 244–248, 1996, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55921.