The facile synthesis of cyclopentanoid antibiotic kjellmanianone

Demir, Ayhan Sıtkı
Tanyeli, Cihangir
Gulbeyaz, V
Akgul, H
The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate beta-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.


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Citation Formats
A. S. Demir, C. Tanyeli, V. Gulbeyaz, and H. Akgul, “The facile synthesis of cyclopentanoid antibiotic kjellmanianone,” TURKISH JOURNAL OF CHEMISTRY, pp. 244–248, 1996, Accessed: 00, 2020. [Online]. Available: