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The facile synthesis of cyclopentanoid antibiotic kjellmanianone
Date
1996-01-01
Author
Demir, Ayhan Sıtkı
Tanyeli, Cihangir
Gulbeyaz, V
Akgul, H
Metadata
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate beta-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.
Subject Keywords
MANGANESE(III) ACETATE
,
CARBOXYLIC-ACIDS
,
COMBINATION
,
OXIDATION
,
ENONES
URI
https://hdl.handle.net/11511/55921
Journal
TURKISH JOURNAL OF CHEMISTRY
Collections
Department of Chemistry, Article
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A. S. Demir, C. Tanyeli, V. Gulbeyaz, and H. Akgul, “The facile synthesis of cyclopentanoid antibiotic kjellmanianone,”
TURKISH JOURNAL OF CHEMISTRY
, pp. 244–248, 1996, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55921.