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Enantioselective synthesis of hydroxy ketones through cleavage and formation of acyloin linkage. Enzymatic kinetic resolution via C-C bond cleavage
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Date
2001-01-01
Author
Demir, Ayhan Sıtkı
Pohl, M
Janzen, E
Muller, M
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Both enantiomers of benzoins and (R)-2-hydroxy-1-phenylpropanone analogues were obtained in high yield on a preparative scale starting from aromatic aldehydes, rac-benzoins and aliphatic aldehydes via enzyme-catalysed C-C bond cleavage and C-C bond formation reactions.
Subject Keywords
Benzoylformate decarboxylase
,
Dependent enzymes
,
Organic synthesis
,
Aldolase
,
Thiamin
,
Diphosphate
,
Benzoin
,
Acids
URI
https://hdl.handle.net/11511/56453
Journal
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
DOI
https://doi.org/10.1039/b100341k
Collections
Department of Chemistry, Article