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Enantioselective synthesis of hydroxy ketones through cleavage and formation of acyloin linkage. Enzymatic kinetic resolution via C-C bond cleavage

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2001-01-01
Demir, Ayhan Sıtkı
Pohl, M
Janzen, E
Muller, M
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This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
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Both enantiomers of benzoins and (R)-2-hydroxy-1-phenylpropanone analogues were obtained in high yield on a preparative scale starting from aromatic aldehydes, rac-benzoins and aliphatic aldehydes via enzyme-catalysed C-C bond cleavage and C-C bond formation reactions.
Benzoylformate decarboxylase, Dependent enzymes, Organic synthesis, Aldolase, Thiamin, Diphosphate, Benzoin, Acids
https://hdl.handle.net/11511/56453

Department of Chemistry, Article
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