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Alkylation of l- and d-menthyl pentanoate with (20S)-20-iodomethyl-4 alpha-methyl-5 alpha-pregnane
Date
1996-01-01
Author
Demir, Ayhan Sıtkı
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The alkylation of l- and d-menthyl valerate with n-hexyl iodide and with (20S)-20-iodomethyl-4 alpha-methyl-5 alpha-pregnane gave modest levels of diastereoselection. The chirality of the ester group favoured slight degree of selectivity. The chiral centers had limited impact on diastereoselectivity.
Subject Keywords
Organic Chemistry
URI
https://hdl.handle.net/11511/56772
Journal
SYNTHETIC COMMUNICATIONS
DOI
https://doi.org/10.1080/00397919608004775
Collections
Department of Chemistry, Article
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A. S. Demir, “Alkylation of l- and d-menthyl pentanoate with (20S)-20-iodomethyl-4 alpha-methyl-5 alpha-pregnane,”
SYNTHETIC COMMUNICATIONS
, pp. 4519–4530, 1996, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/56772.