Alkylation of l- and d-menthyl pentanoate with (20S)-20-iodomethyl-4 alpha-methyl-5 alpha-pregnane

Date

1996-01-01

Author

Demir, Ayhan Sıtkı

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The alkylation of l- and d-menthyl valerate with n-hexyl iodide and with (20S)-20-iodomethyl-4 alpha-methyl-5 alpha-pregnane gave modest levels of diastereoselection. The chirality of the ester group favoured slight degree of selectivity. The chiral centers had limited impact on diastereoselectivity.

Subject Keywords

Organic Chemistry

URI

https://hdl.handle.net/11511/56772

Journal

SYNTHETIC COMMUNICATIONS

DOI

https://doi.org/10.1080/00397919608004775

Collections

Department of Chemistry, Article

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Citation Formats

A. S. Demir, “Alkylation of l- and d-menthyl pentanoate with (20S)-20-iodomethyl-4 alpha-methyl-5 alpha-pregnane,” SYNTHETIC COMMUNICATIONS, pp. 4519–4530, 1996, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/56772.