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Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)
Date
2006-05-29
Author
Celik, Murat
Alp, Cemalettin
Coşkun, Betül
Gultekin, M. Serdar
Balcı, Metin
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1.2- and 1.3-Bis(trifluoroacetoxy) alcohols are easily obtained from the one-pot reaction of alkenes with phenyliodine(III) bis(trifluoroacetate) (PIFA) in the absence of any additive or catalyst. The products were converted into the corresponding diols by ammonolysis. The use of bicyclic alkenes has shown that rearranged 1,3-diacetoxy alcohols are mostly formed as the major products.
Subject Keywords
Phenyliodine(III) bis(trifluoroacetate)
,
PIFA
,
Oxidation
,
Rearrangement
,
1.2-diols
,
1.3-diols
URI
https://hdl.handle.net/11511/57166
Journal
TETRAHEDRON LETTERS
DOI
https://doi.org/10.1016/j.tetlet.2006.03.137
Collections
Department of Physical Education and Sports, Article
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M. Celik, C. Alp, B. Coşkun, M. S. Gultekin, and M. Balcı, “Synthesis of diols using the hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate),”
TETRAHEDRON LETTERS
, pp. 3659–3663, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/57166.