Efficient rearrangement of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)(6)(H2O)(3)]

Date

2010-03-27

Author

Erturk, Erkan
Gollu, Mehmet
Demir, Ayhan Sıtkı

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The mixed-valent oxo-centered triiron(III, III, II) trifluoroacetate complex [(Fe2FeO)-Fe-III-O-II(C2CCF3)(6)(H2O)(3)] Was prepared by reacting anhydrous iron(III) chloride with boiling trifluoroaceric acid under nitrogen. The non-hygroscopic and readily available mixed-valent triiron trifluoroacetate complex Was found to be an efficient catalyst for the regioselective rearrangement of epoxides. A number of carbonyl compounds formed via the rearrangement of epoxides could be obtained by a simple filtration of the reaction mixture through a short plug of silica gel.

Subject Keywords

Organic Chemistry, Biochemistry, Drug Discovery

URI

https://hdl.handle.net/11511/62767

Journal

TETRAHEDRON

DOI

https://doi.org/10.1016/j.tet.2010.01.102

Collections

Department of Chemistry, Article

Citation Formats

E. Erturk, M. Gollu, and A. S. Demir, “Efficient rearrangement of epoxides catalyzed by a mixed-valent iron trifluoroacetate [Fe3O(O2CCF3)(6)(H2O)(3)],” TETRAHEDRON, vol. 66, no. 13, pp. 2373–2377, 2010, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62767.