Synthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride

Date

2011-05-31

Author

BAYSAL, AKIN
AYDEMİR, MURAT
DURAP, FEYYAZ
Özkar, Saim
Yildirim, Leyla Tatar

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Condensation reaction of 2,9-dicarboxaldehyde-1,10-phenanthroline with 2-aminoethanol followed by NaBH4 reduction yielded the polydentate Schiff base ligand 2,9-bis(ethanolamine)-1,10-phenanthroline in its reduced form. This ligand was characterized by elemental analysis, LC-MS, IR, UV-Vis and NMR spectroscopy. Reaction of the reduced Schiff base ligand with aqueous solution of cobalt(II) chloride affords 2,9-bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride in high yield. Single crystals of the cobalt(II) complex were obtained from the crystallization in ethanol and its structure was elucidated by X-ray structural analysis. The cobalt(II) complex ion was found to be seven-coordinated in a pentagonal bipyramidal geometry, whereby cobalt(II) ion is surrounded by the six donor atoms in the ligand molecule and a chloride ion. (C) 2011 Elsevier B. V. All rights reserved.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Materials Chemistry

URI

https://hdl.handle.net/11511/62992

Journal

INORGANICA CHIMICA ACTA

DOI

https://doi.org/10.1016/j.ica.2011.03.050

Collections

Department of Chemistry, Article

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Citation Formats

A. BAYSAL, M. AYDEMİR, F. DURAP, S. Özkar, and L. T. Yildirim, “Synthesis and structural characterization of a novel seven-coordinate cobalt(II) complex: 2,9-Bis(ethanolamine)-1,10-phenanthrolinechlorocobalt(II) chloride,” INORGANICA CHIMICA ACTA, pp. 107–110, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62992.