Zeolite framework stabilized nickel(0) nanoparticles: Active and long-lived catalyst for hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride

Date

2011-07-19

Author

Zahmakiran, Mehmet
Ayvali, Tugce
Akbayrak, Serdar
Caliskan, Salim
Celik, Derya
Özkar, Saim

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Among the hydrogen storage materials, ammonia-borane and sodium borohydride appear to be promising candidates as they can release hydrogen on hydrolysis in aqueous solution under mild conditions. Here, we report the development of a cost-effective and highly active nickel(0) nanoparticles catalyst for the hydrolysis of ammonia-borane and sodium borohydride. Nickel(0) nanoparticles confined in zeolite framework were prepared by using our previously established procedure and characterized by ICP-OES, XRD, TEM, HR-TEM, SEM, EDX, XPS, Raman spectroscopy and N(2) adsorption-desorption technique. All the results show that nickel(0) nanoparticles are formed within the framework of zeolite-Y. Nickel(0) nanoparticles confined in zeolite framework are highly active catalyst in the hydrolytic dehydrogenations of sodium borohydride and ammonia-borane. This catalyst is isolable, bottleable, redispersible and reusable. The report also includes the detailed kinetic study of the catalytic hydrolysis of both substrates, ammonia-borane and sodium borohydride depending on the catalyst concentration, substrate concentration, and temperature.

Subject Keywords

General Chemistry, Catalysis

URI

https://hdl.handle.net/11511/63002

Journal

CATALYSIS TODAY

DOI

https://doi.org/10.1016/j.cattod.2010.09.022

Collections

Department of Chemistry, Article

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Citation Formats

M. Zahmakiran, T. Ayvali, S. Akbayrak, S. Caliskan, D. Celik, and S. Özkar, “Zeolite framework stabilized nickel(0) nanoparticles: Active and long-lived catalyst for hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride,” CATALYSIS TODAY, pp. 76–84, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/63002.