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Synthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexes
Date
2008-01-20
Author
DURAP, FEYYAZ
BİRİCİK, NERMİN
Guemguem, Bahattin
Özkar, Saim
Ang, Wee Han
Fei, Zhaofu
Scopelliti, Rosario
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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N,N-Bis(diphenylphosphino)ethylaniline compounds, [Ph2P](2)N-C6H4-C2H5, with ethyl groups at the ortho- and para-positions have been synthesized. Oxidation of the aminophosphines with hydrogen peroxide, elemental sulfur and selenium gave the corresponding oxides, sulfides and selenides [Ph2P(E)](2)N-C6H4-C2H5 (E = O, S, Se). Complexes [MCl2{(Ph2P)(2)N-C6H4-(C2H5)}] (M = Pd, Pt) and [Cu{(Ph2P)(2)N-C6H4-C2H5)(2)]PF6 were obtained by the reaction of NN-bis(diphenylphosphino)ethylaniline with [MCl2(COD)] (M = Pd, Pt) and (Cu(MeCN)(4)]PF6. The new compounds were characterized by NMR, IR spectroscopy and microanalysis. In addition, representative solid-state structures of the palladium and platinum complexes were determined using single crystal X-ray diffraction analyses.
Subject Keywords
Aminophosphine
,
X-ray structures
,
Complexation
,
Oxidation
,
Synthesis
URI
https://hdl.handle.net/11511/63029
Journal
POLYHEDRON
DOI
https://doi.org/10.1016/j.poly.2007.09.011
Collections
Department of Chemistry, Article
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F. DURAP et al., “Synthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexes,”
POLYHEDRON
, pp. 196–202, 2008, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/63029.