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Low-temperature chemical synthesis of lanthanum monoaluminate
Date
1997-01-01
Author
Taspinar, E
Tas, AC
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One of the promising candidates for ferroelectric substrate materials, lanthanum monoaluminate (LaAlO3), was successfully synthesized by two separate chemical powder preparation techniques: (i) homogeneous precipitation from aqueous solutions containing urea (CH4N2O) in the presence of nitrate salts, and (ii) self-propagating combustion synthesis from aqueous solutions containing CH4N2O and the respective nitrate salts of lanthanum and aluminum. The submicrometer, spherical-like particles of the precursors were completely converted to pure LaAlO3 at 850 degrees C in the homogeneous precipitation route, and the same conversion temperature was observed to be 750 degrees C, which becomes the lowest temperature ever reported for the powder synthesis of a pure LaAlO3 phase. The materials were characterized by powder X-ray diffractometry, simultaneous thermogravimetric/differential thermal analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Structural refinements by Rietveld analysis showed that LaAlO3 was isostructural with BaTbO3 and had the space group R-3c, in contrast to the previously assumed space group of R-3m for this phase. The atomic positions in the structure of LaAlO3 were refined and presented for the first time, with respect to the present space group.
Subject Keywords
Materials Chemistry
,
Ceramics and Composites
URI
https://hdl.handle.net/11511/64613
Journal
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
DOI
https://doi.org/10.1111/j.1151-2916.1997.tb02801.x
Collections
Department of Metallurgical and Materials Engineering, Article
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E. Taspinar and A. Tas, “Low-temperature chemical synthesis of lanthanum monoaluminate,”
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
, pp. 133–141, 1997, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/64613.