POLYMERIZATION OF BIS(4-BROMO-2,6-DICHLOROPHENOXO) ETHYLENEDIAMINE COPPER(II) COMPLEX BY ELECTRO-INITIATION

1991-01-01
KISAKUREK, D
YIGIT, S
Bis(4-bromo-2,6-dichlorophenoxo) ethylenediamine copper(II) complex has been polymerized using electro-initiation by constant potential electrolysis, in dimethylformamide-tetrabutylammonium fluoroborate solvent-supporting electrolyte couple, at room temperature under air or N2. The process leads to low molecular weight (5.6 x 10(3)) linear poly(dichlorophenylene oxide). The structures of the polymers were determined by H-1-NMR and C-13-NMR. The kinetics of the polymerization were followed by in situ cyclic voltammetry measurements during electrolysis. Unlike thermal polymerization of this complex, the polymerization by electro-initiation begins immediately.
EUROPEAN POLYMER JOURNAL

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Citation Formats
D. KISAKUREK and S. YIGIT, “POLYMERIZATION OF BIS(4-BROMO-2,6-DICHLOROPHENOXO) ETHYLENEDIAMINE COPPER(II) COMPLEX BY ELECTRO-INITIATION,” EUROPEAN POLYMER JOURNAL, pp. 955–958, 1991, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/65500.