POLYMERIZATION OF BIS(4-BROMO-2,6-DICHLOROPHENOXO) ETHYLENEDIAMINE COPPER(II) COMPLEX BY ELECTRO-INITIATION

Date

1991-01-01

Author

KISAKUREK, D
YIGIT, S

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Bis(4-bromo-2,6-dichlorophenoxo) ethylenediamine copper(II) complex has been polymerized using electro-initiation by constant potential electrolysis, in dimethylformamide-tetrabutylammonium fluoroborate solvent-supporting electrolyte couple, at room temperature under air or N2. The process leads to low molecular weight (5.6 x 10(3)) linear poly(dichlorophenylene oxide). The structures of the polymers were determined by H-1-NMR and C-13-NMR. The kinetics of the polymerization were followed by in situ cyclic voltammetry measurements during electrolysis. Unlike thermal polymerization of this complex, the polymerization by electro-initiation begins immediately.

Subject Keywords

Organic Chemistry, General Physics and Astronomy, Polymers and Plastics

URI

https://hdl.handle.net/11511/65500

Journal

EUROPEAN POLYMER JOURNAL

DOI

https://doi.org/10.1016/0014-3057(91)90039-q

Collections

Department of Chemistry, Article

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Citation Formats

D. KISAKUREK and S. YIGIT, “POLYMERIZATION OF BIS(4-BROMO-2,6-DICHLOROPHENOXO) ETHYLENEDIAMINE COPPER(II) COMPLEX BY ELECTRO-INITIATION,” EUROPEAN POLYMER JOURNAL, pp. 955–958, 1991, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/65500.