EFFECT OF ION ASSOCIATION ON THE PROPERTIES OF IONOMERS OBTAINED FROM METHYL-METHACRYLATE METHACRYLIC-ACID COPOLYMER

Date

1990-07-01

Author

KOCAK, HI
ARAS, L

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The solution behaviour of Na, Ba, Zn and Al ionomers of methyl methacrylate-methacrylic acid copolymer (P(MMA-MAA)) with different ion contents has been studied by viscosity and dipole moment measurements. Two solvents with different character are chosen for viscosity measurements: dioxane (ε = 2.22) and acetone (ε = 20.7). The expected polyelectrolyte behaviour of the ionomers in acetone is reflected by the viscometric measurements. Mean squared dipole moment 〈μ2〉 values are calculated over a temperature range of 20–100°C in dioxane. Effects of neutralization, cation size and cation charge are discussed for each ionomer.

Subject Keywords

Organic Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/65831

Journal

POLYMER

DOI

https://doi.org/10.1016/0032-3861(90)90225-n

Collections

Department of Chemistry, Article

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Citation Formats

H. KOCAK and L. ARAS, “EFFECT OF ION ASSOCIATION ON THE PROPERTIES OF IONOMERS OBTAINED FROM METHYL-METHACRYLATE METHACRYLIC-ACID COPOLYMER,” POLYMER, pp. 1328–1332, 1990, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/65831.