ALTERNATING CYCLOPOLYMERIZATION OF ALLYL TRANS-CINNAMATE AND MALEIC-ANHYDRIDE

Date

1994-01-01

Author

RZAEV, ZMO
AKOVALI, G
MEDYAKOVA, LV

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Some features of the radical copolymerization of allyl cinnamate bifunctional monomers, containing donor (allyl)-acceptor (beta-phenylacryl) double bonds in the molecule, with maleic anhydride have been revealed. The kinetic parameters of the reactions, including their complex-formation, cyclization and copolymerization constants, as well as the ratios of chain growth rates for the participation of monomeric charge-transfer complexes and free monomers, are all determined. It has been established that an alternative cyclocopolymerization reaction is realized, which is carried out via a complex mechanism with the formation of macromolecules with unsaturated cycle-linear structures. The synthesized copolymers show high sensitivity to ultraviolet irradiation, electron beams and X-rays, but their negative resists differed, with high lithographic parameters and plasma stability.

Subject Keywords

Organic Chemistry, Polymers and Plastics

URI

https://hdl.handle.net/11511/66937

Journal

POLYMER

DOI

https://doi.org/10.1016/0032-3861(94)90489-8

Collections

Department of Chemistry, Article

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Citation Formats

Z. RZAEV, G. AKOVALI, and L. MEDYAKOVA, “ALTERNATING CYCLOPOLYMERIZATION OF ALLYL TRANS-CINNAMATE AND MALEIC-ANHYDRIDE,” POLYMER, pp. 5349–5354, 1994, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/66937.