SOLID-STATE POLYMERIZATION OF BIS(TRICHLOROPHENOXO) COBALT(II) COMPLEX TO GIVE POLY(DICHLOROPHENYLENE OXIDE)

Date

1993-01-01

Author

BASTURKMEN, M
ISCI, H
KISAKUREK, D

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Synthesis of four-coordinated (tetrahedral) trichlorophenol cobalt(II) complex with neutral ligand pyridine was achieved from the aqueous solution and its characterization was performed by UV-visible, IR spectral and CHN analysis. Solid state thermal polymerization of the complex was accomplished first at constant temperature employing different time intervals and secondly at constant decomposition time. The poly(dichlorophenylene oxide)s so synthesized were characterized by IR, H-1 NMR and C-13 NMR spectral analysis, T(g) determination, as well as measurement of molecular weight by a viscometric method.

Subject Keywords

Polymers and Plastics

URI

https://hdl.handle.net/11511/67206

Journal

POLYMER INTERNATIONAL

DOI

https://doi.org/10.1002/pi.4990300319

Collections

Department of Chemistry, Article

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Citation Formats

M. BASTURKMEN, H. ISCI, and D. KISAKUREK, “SOLID-STATE POLYMERIZATION OF BIS(TRICHLOROPHENOXO) COBALT(II) COMPLEX TO GIVE POLY(DICHLOROPHENYLENE OXIDE),” POLYMER INTERNATIONAL, pp. 387–392, 1993, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/67206.