Spectroscopic and crystal structure analysis of diamminebis(2,4,6-triiodophenolato-O) copper(II)

Date

2006-05-01

Author

Gokagac, Gulsun
Yildirim, Leyla Tatar
Sonsuz, Muammer
Sen, Fatih

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The crystal structure of [Cu(C6H2I3O)(2)(NH3)(2)] (CCDC 238896) has been determined by x-ray diffraction. This monomeric centrosymmetric Cu(II) complex crystallizes in the monoclinic system. The CuO2N2 coordination sphere is trans-planar, [Cu-O: 1.943(5) angstrom and Cu-N: 1.972(7)] with the fifth and sixth coordination sites occupied by I atoms from the phenoxide ions [Cu-I-1: 3.3552(8) angstrom] to form a tetragonally elongated octahedral structure for CuO2N2I2 Coordination. The complex molecules hold together in a one dimensional chain true [100] direction by intermolecular hydrogen bonds. Differential scanning calorimeter, FTIR and magnetic susceptibility measurements were also performed in order to identify the title complex.

Subject Keywords

General Materials Science, General Chemistry, Condensed Matter Physics

URI

https://hdl.handle.net/11511/67826

Journal

CRYSTAL RESEARCH AND TECHNOLOGY

DOI

https://doi.org/10.1002/crat.200510616

Collections

Department of Chemistry, Article

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Citation Formats

G. Gokagac, L. T. Yildirim, M. Sonsuz, and F. Sen, “Spectroscopic and crystal structure analysis of diamminebis(2,4,6-triiodophenolato-O) copper(II),” CRYSTAL RESEARCH AND TECHNOLOGY, pp. 523–527, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/67826.