Instability phenomenon originated from the disordered layer of the plasma-deposited BN film/c-Si interface assessed through the MIS structure by admittance measurement

2008-02-01
Oezdemir, Orhan R.
Anutgan, Mustafa
Aliyeva-Anutgan, Tamila
Atilgan, Ismail
Katircioglu, Bayram
A plasma enhanced chemical vapor-deposited (PECVD) boron nitride (BN) film on p-type crystalline silicon (p-c-Si) was used to fabricate the metal-insulator-semiconductor (MIS) test structure. The effects of positive (inverting type) and negative (accumulating type) bias stresses on the MIS (Al/BN/p-Si/Al) structure were investigated as a function of time, bias voltage stresses and temperature. Charge injection into the gate dielectric (BN film in this case) was considered as a mechanism to provoke the instability problem that manifested itself as a slow shift of specific voltage (Delta V-HH) which symbolizes the whole capacitance-gate bias voltage (C-V) curve. Moreover, the evolution of this shift is followed by monitoring Delta V-HH as a function of time, temperature and gate voltage stress and fitted to a functional form for the Delta V-HH shift kinetics. Good agreement with the experimental data confirms the charge injection hypothesis behind the shift in C-V curves. Finally, the origin of an eventual defective structure, required by the actual instability, is argued in terms of possible chemical composition of the film. Seemingly BN possesses a turbostratic structure; the first layer at the initial stage in growth is amorphous (even self-doped by a contamination from the underlying silicon substrate) on which a more ordered phase might continue.
SEMICONDUCTOR SCIENCE AND TECHNOLOGY

Suggestions

Characteristics of HfO2 and SiO2 on p-type silicon wafers using terahertz spectroscopy
Altan, Hakan; Pham, D.; Grebel, H.; Federici, J. F. (IOP Publishing, 2007-05-01)
The effect of high-kappa dielectric HfO2 films on 200 mm diameter p-type silicon substrates was investigated and compared with conventional dielectric material, SiO2. We employed all-optical characterization methods using terahertz (THz) time-domain spectroscopy and visible cw pump/THz probe spectroscopy. Measurements were performed on two sets of samples, each set containing both HfO2 and SiO2 coated wafers with varying thickness of oxide layer. One set had a protective coating of either photoresist or Si3...
Frequency effect on electrical and dielectric characteristics of HfO2-interlayered Si-based Schottky barrier diode
Gullu, H. H.; Yildiz, D. E.; Surucu, O.; Parlak, Mehmet (Springer Science and Business Media LLC, 2020-06-01)
This study reveals the electrical properties of In/HfO2/n-Si structure with atomic layer-deposited interfacial oxide layer, HfO2 thin film between In top metal contact and monocrystalline Si wafer substrate. From the dark current-voltage measurements, the diode structure showed good rectifying behavior and low saturation current of about two order of magnitude and 1.2 x 10(- 9) A, respectively. According to the conventional thermionic emission model, zero-bias barrier height and ideality factor were calcula...
Optical properties of (Ga2Se3)(0.)(75) - (Ga2S3)(0.)(25) single crystals by spectroscopic ellipsometry
Işık, Mehmet; Hasanlı, Nızamı; Gasanova, L. (Elsevier BV, 2019-05-01)
Structural and optical properties of 75 mol % Ga2Se3 - 25 mol % Ga2S3 system of single crystals were investigated by experimental techniques of x-ray diffraction (XRD), energy dispersive spectroscopy, Raman spectroscopy and ellipsometry. XRD pattern indicated that the studied compound has crystalline nature with cubic structure. Vibrational modes in the crystal were revealed using Raman spectroscopy experiments in the 90-450 cm(-1) frequency range and nine modes were observed in the spectrum. Ellipsometry m...
STRUCTURAL STABILITY AND ENERGETICS OF FCC METAL MICROCLUSTERS - EMPIRICAL MANY-BODY POTENTIAL-ENERGY FUNCTION CALCULATION
Erkoç, Şakir (Wiley, 1990-09-01)
The structural stability and energetics of microclusters containing 3 to 7 atoms of f.c.c. metal elements are investigated. A recently developed empirical many‐body potential function (PEF) is used in the calculations, which comprises two‐ and threebody atomic interactions. The PEF satisfies both, bulk cohesive energy and stability condition. It is found that the energetically most stable structures of microclusters are in compact form.
Phase Identification of La-Doped Hard Magnetic Barium Ferrite Using Artificial Neural Network
Sozeri, Huseyin; KÜÇÜK, İLKER; Ozkan, Husnu (Springer Science and Business Media LLC, 2011-01-01)
A model based on an artificial neural network (ANN) was designed for the simulation and estimation of 2 theta and intensity values obtained by X-Ray Diffraction (XRD) of pure and La-doped barium ferrite powders which have been synthesized in ammonium nitrate melt. Its performance is evaluated by the influences of different La content, sintering temperature, Fe/Ba ratio, and washed in HCl (or not washed in HCl) samples. The XRD patterns of samples estimated by the ANN agree well with the experimental values,...
Citation Formats
O. R. Oezdemir, M. Anutgan, T. Aliyeva-Anutgan, I. Atilgan, and B. Katircioglu, “Instability phenomenon originated from the disordered layer of the plasma-deposited BN film/c-Si interface assessed through the MIS structure by admittance measurement,” SEMICONDUCTOR SCIENCE AND TECHNOLOGY, pp. 0–0, 2008, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/68104.