BOROPHOSPHATES - A NEGLECTED CLASS OF COMPOUNDS - CRYSTAL-STRUCTURES OF M(II)[BPO5] (M(II)=CA, SR) AND BA-3[BP3O12]

Date

1994-04-18

Author

KNIEP, R
GOZEL, G
EISENMANN, B
ROHR, C
ASBRAND, M
KIZILYALLI, M

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Vertex‐sharing BO4 and PO4 tetrahedra form the framework of the title compounds. Ca[BPO5] and Sr[BPO5] crystallize in the stillwellite structural type and contain tetrahedral chain anions urn:x-wiley:05700833:media:ANIE199407491:tex2gif-stack-1[BPOurn:x-wiley:05700833:media:ANIE199407491:tex2gif-stack-2], which can be described as loop‐branched “dreier” single chains. In Ba3[BP3O12] the urn:x-wiley:05700833:media:ANIE199407491:tex2gif-stack-3tetrahedral anions form “zweifach” open “vierer” single chains. Given these results and the known linking modes of tetrahedral units, it is expected that borophosphates with layered and framework structures, as well as microporous structures, can be found.

Subject Keywords

General Chemistry, Catalysis

URI

https://hdl.handle.net/11511/68328

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

DOI

https://doi.org/10.1002/anie.199407491

Collections

Department of Chemistry, Article

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Citation Formats

R. KNIEP, G. GOZEL, B. EISENMANN, C. ROHR, M. ASBRAND, and M. KIZILYALLI, “BOROPHOSPHATES - A NEGLECTED CLASS OF COMPOUNDS - CRYSTAL-STRUCTURES OF M(II)[BPO5] (M(II)=CA, SR) AND BA-3[BP3O12],” ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, pp. 749–751, 1994, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/68328.