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Electronic absorption spectra of some binuclear and mononuclear complexes of platinum, palladium and nickel with bidentate sulfur donor ligands.
Date
1989
Author
Dağ, Ömer
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https://hdl.handle.net/11511/8736
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Graduate School of Natural and Applied Sciences, Thesis
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Electronic absorption and 7-T magnetic circular dichroism (MCD) spectra in the UV-visible region are reported for the binuclear diplatinum(III) ions: Pt2(SO4)4X2n-, n = 2, X = H2O, NH3; n = 4, X = Cl-, Br-, OH-. Pt2(HPO4)4X2n-, n = 2, X = H2O, Me2S; n = 4, X = Cl-, Br-. Both the absorption spectra and the MCD spectra for complexes with the same axial ligand X are similar for oxo-bridging SO42- or HPO42-. However, the MCD spectra show marked differences depending upon the nature of the X ligand. The mos...
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Ö. Dağ, “Electronic absorption spectra of some binuclear and mononuclear complexes of platinum, palladium and nickel with bidentate sulfur donor ligands.,” Middle East Technical University, 1989.