Synthesis and characterization of poly (dichlorophenylene oxides) through solid state thermal decomposition of bis(pyridine) bis(trichlorophenoxo) copper (II) and bis (pyridine) bis (trichlorophenoxo) Cobalt(II) complexes

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1991
Baştürkmen, Meray

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SYNTHESIS AND CHARACTERIZATION OF POLY(DICHLOROPHENYLENE OXIDE)S THROUGH SOLID-STATE THERMAL-DECOMPOSITION OF BIS(PYRIDINE)BIS(TRICHLOROPHENOXO)COPPER(II) COMPLEXES
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Thermal polymerization of bis(pyridine)bis(trichlorophenoxo)copper(II) was achieved in the solid state for the first time. The time and temperature effect on polymer molecular weight, percentage yield and the structure of polymer was first studied, at constant temperature and then for constant decomposition time. Polymers were characterized by i.r., H-1 n.m.r. and C-13 n.m.r. The molecular weights of the polymers were obtained by viscometric measurements at 30-degrees-C in toluene and glass transition tempe...
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Citation Formats
M. Baştürkmen, “Synthesis and characterization of poly (dichlorophenylene oxides) through solid state thermal decomposition of bis(pyridine) bis(trichlorophenoxo) copper (II) and bis (pyridine) bis (trichlorophenoxo) Cobalt(II) complexes,” Middle East Technical University, 1991.