Palladium nanoparticles supported on cobalt(II,III) oxide nanocatalyst: High reusability and outstanding catalytic activity in hydrolytic dehydrogenation of ammonia borane

Date

2022-11-01

Author

Akbayrak, Serdar
Özkar, Saim

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A new palladium(0) nanocatalyst is developed to enhance the catalytic efficiency of precious metal catalysts in hydrogen generation from the hydrolytic dehydrogenation of ammonia borane. Magnetically separable Pd-0/Co3O4 nanocatalyst can readily be obtained by the reduction of palladium(II) cations impregnated on cobalt(II, III) oxide at room temperature. The obtained Pd-0/Co3O4 nanocatalyst with 0.25% wt. palladium loading has outstanding catalytic activity with a record turnover frequency of 3048 min(-1) in the releasing H-2 from the hydrolysis of ammonia borane at 25.0 degrees C. They also provide out-standing reusability even after the tenth run of the hydrolysis of ammonia borane at 25.0 degrees. The high activity and superb stability of magnetically isolable Pd-0/Co3O4 nanoparticles are attributed to the favor-able interaction of palladium with the surface of reducible cobalt oxide. (C) 2022 Elsevier Inc. All rights reserved.

Subject Keywords

Palladium nanoparticles, Cobalt(II,III) oxide, Magnetic nanocatalyst, Dehydrogenation, Ammonia borane, HYDROGEN GENERATION, REUSABLE CATALYST, RU NANOCLUSTERS, H-2 GENERATION, GRAPHENE, EFFICIENT, PD, EVOLUTION, SURFACE, SYSTEM

URI

https://hdl.handle.net/11511/99064

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE

DOI

https://doi.org/10.1016/j.jcis.2022.06.135

Collections

Department of Chemistry, Article

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Citation Formats

S. Akbayrak and S. Özkar, “Palladium nanoparticles supported on cobalt(II,III) oxide nanocatalyst: High reusability and outstanding catalytic activity in hydrolytic dehydrogenation of ammonia borane,” JOURNAL OF COLLOID AND INTERFACE SCIENCE, vol. 626, pp. 752–758, 2022, Accessed: 00, 2022. [Online]. Available: https://hdl.handle.net/11511/99064.