Synthesis and characterization of poly (4-vinylpyridine)-poly(dimethylsiloxane) block copolymers and electrical conductivity of their charge transfer complexes

Nugay, Nihan


Preparation and characterization of butadiene-styrene and ethylene oxide-styrene block copolymers.
Orhan, Erdal H; Baysal, Bahattin; Department of Chemistry (1975)
Synthesis of conducting copolymer of succinic acid bis-(pyrrolyl-phenyl) ester with thiophene
Ertaş, Merve; Toppare, Levent Kamil; Hacaloğlu, Jale; Department of Chemistry (2003)
Synthesis and characterization of conducting block copolymers of thiophene-ended polystyrene with polypyrrole
Alkan, S; Toppare, Levent Kamil; Hepuzer, Y; Yagci, Y (2001-03-15)
4,4' Azobis 4-cyano3-thiophenemethyl pentanate (ACTMP) was synthesized from 3-Thiophenemethanol and 4,4'-Azobis (4-cyanopentanoyl chloride). ACTMP was further used in the synthesis of polystyrene with thiophene terminal groups (TPSt) at both ends. Conducting block copolymers of TPSt and pyrrole (TPSt/PPy) were electrochemically prepared using several supporting electrolytes. Characterization of these block copolymers were performed.
Synthesis and characterization of thiophen-3-yl-acetic acid 4-pyrrol-1-yl-phenyl ester and its conducting polymers
Bingöl, Bahar; Toppare, Levent Kamil; Department of Chemistry (2003)
Thiophen-3-yl acetic acid 4-pyrrol-1-yl phenyl ester (TAPE) monomer was synthesized by the reaction of thiophene acetic acid with thionyl chloride, and further reaction of thiophen-3-yl-acetyl chloride with 4-pyrrol-1-yl phenol. Electrochemical behavior of this monomer (TAPE) was determined by cyclic voltammetry. Homopolymers were achieved both by using electrochemical and chemical polymerization techniques. Copolymers of TAPE in the presence of bithiophene and pyrrole were synthesized by potentiostatic ele...
Synthesis of conducting graft copolymers of 2-(N-pyrrolyl)ethylvinyl ether with pyrrole
Bengu, B; Toppare, Levent Kamil; Kalaycioglu, E (2001-01-01)
2-(N-pyrrolyl)ethylvinyl ether (2-NEVE) was synthesized from 2-chloroethylvinyl ether (2-CEVE) via a phase catalysis reaction. Cyclic voltammetric studies were carried out to check for the electroactivity of 2-NEVE. Poly(2-(N-pyrrolyl)ethylvinyl ether) [poly(2-NEVE)] was synthesized via chemical methods. Graft copolymers of pyrrole and 2-NEVE were synthesized by electrochemical methods. The chemical structures of 2-NEVE and poly(2-NEVE) were investigated by several spectroscopic methods. Graft copolymers we...
Citation Formats
N. Nugay, “Synthesis and characterization of poly (4-vinylpyridine)-poly(dimethylsiloxane) block copolymers and electrical conductivity of their charge transfer complexes,” Ph.D. - Doctoral Program, Middle East Technical University, 1992.