Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Production and characterization of activated carbon from apricot stones
Download
index.pdf
Date
2004
Author
Yağşi, Nezih Ural
Metadata
Show full item record
Item Usage Stats
434
views
178
downloads
Cite This
In this study, characterization of activated carbon produced from apricot stones by chemical activation technique using phosphoric acid (H3PO4) as activating agent, at relatively low temperatures (300, 400 and 500oC), was investigated. To produce activated carbon acid impregnated samples were heated; at a heating rate of 20oC/min to the final carbonization temperatures, 300oC, 400oC and 500oC. For each temperature four different carbonization time (90, 120, 180 and 210 min.) were used to produce twelve different activated carbons. The pore structures of activated carbons were determined as follows: The volume and area of macropores in the pore diameter range of 8180-50 nm were determined by mercury intrusion porosimetry. Mesopore (in the range of 50-2 nm) areas and volumes were determined by N2 gas adsorption technique at -195.6oC, BET surface areas of the samples were also determined, in the relative pressure range of 0.05 to 0.02, by the same technique. The pore volume and the area of the micropores with diameters less than 2 nm were determined by CO2 adsorption measurements at 0oC by the application of Dubinin Radushkevich equation. N2 (BET) and CO2 (D-R) surface areas of the samples were in the range of 444-709m2/g and 433-650m2/g, respectively. AC4.2 sample (carbonization temperature of 400oC and carbonization time of 120 min.) was found to have the maximum BET and CO2 area as 709m2/g and 650m2/g, respectively. Surface areas of the samples consisting of around 10% mesopores and over 90% micropores. N2 adsorption isotherms also confirm that pores are in the micropore range.
Subject Keywords
Manufacture and Use of Chemicals.
URI
http://etd.lib.metu.edu.tr/upload/12604905/index.pdf
https://hdl.handle.net/11511/14120
Collections
Graduate School of Natural and Applied Sciences, Thesis
Suggestions
OpenMETU
Core
Production and characterization of activated carbon from hazelnut shell and hazelnut husk
Çuhadar, Çiğdem; Yücel, Hayrettin; Department of Chemical Engineering (2005)
In this study, the pore structures and surface areas of activated carbons produced from hazelnut shell and hazelnut husk by chemical activation technique using phosphoric acid (H3PO4), at relatively low temperatures (300, 400 and 500oC), were investigated. Raw materials were impregnated with different H3PO4 solutions of 30%, 40%, 50% and 60% by weight. To produce activated carbon, acid impregnated samples were heated; at a heating rate of 20 oC/min to the final carbonization temperature and held at that tem...
Modification of calcium carbonate surfaces in natural gas plasma for their use in polypropylene composite systems
Öztürk, Serhat; Akovalı, Güneri; Department of Polymer Science and Technology (2006)
In this study calcium carbonate (CaCO3) particles are surface modified by using plasma polymerized natural gas and effects of surface modification of CaCO3 filler on mechanical properties of CaCO3-PP composites are investigated. Different combination of plasma factors; RF power, natural gas flow rate, and plasma discharge durations, are investigated. Mechanical properties such as tensile strength and Young’s Modulus are measured by tensile testing machine. Storage modulus and loss modulus measurements are d...
Dynamic and steady-state analysis of oxidative dehydrogenation of ethane
Karamullaoğlu, Gülsün; Doğu, Timur; Department of Chemical Engineering (2005)
In this research, oxidative dehydrogenation of ethane to ethylene was studied over Cr-O and Cr-V-O mixed oxide catalysts through steady-state and dynamic experiments. The catalysts were prepared by the complexation method. By XRD, presence of Cr2O3 phase in Cr-O; and the small Cr2O3 and V2O4 phases of Cr-V-O were revealed. In H2-TPR, both catalysts showed reduction behaviour. From XPS the likely presence of Cr+6 on fresh Cr-O was found. On Cr-V-O, the possible reduction of V+5 and Cr+6 forms of the fresh sa...
DEPENDENCY OF NANOFLUID RHEOLOGY ON PARTICLE SIZE AND CONCENTRATION OF VARIOUS METAL OXIDE NANOPARTICLES
YAPICI, Kerim; Osturk, Ozge; Uludağ, Yusuf (FapUNIFESP (SciELO), 2018-04-01)
Impact of the nanoparticle size and concentration on the rheology of ethylene glycol based nanofluids containing nanoparticles of five different metal oxides is investigated. Particle mass concentrations ranged from 5 to 20 wt %. Types of the nanoparticles and their particle size are TiO2 (30 nm, 50 nm), MgO (20 nm, 40 nm), ZnO (10-30 nm, 35-45 nm, 80-200 nm), SiO2 (20-30 nm, 60-70 nm) and CuO (40 nm, 80 nm). A stress controlled rheometer fitted with a cone-and-plate system is employed for the rheological c...
Artifical photosynthesis : dye assisted photocatalytic reduction of carbon dioxide over pure and platinum containing titania
Özcan, Özlem; Üner, Deniz; Department of Chemical Engineering (2005)
The aim of this study is to test the limits of photocatalytic reduction of CO2 over Pt and light harvesting dye promoted TiO2 films under UV and visible light. Thick and thin TiO2 film catalysts are coated onto 1 cm long glass beads via a common sol-gel procedure and dip coating technique. TiO2 thin films were promoted by Pt and three different light harvesting molecules: RuBpy (Tris (2,2̕ ا bipyridyl) ruthenium (II) chloride hexahydrate) , BrGly (1,7-dibromo-N,N̕-(t-butoxycarbonyl-methyl)-3,4:9,10-perylene...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
N. U. Yağşi, “Production and characterization of activated carbon from apricot stones,” M.S. - Master of Science, Middle East Technical University, 2004.