Disinfection by-products formation in low - bromide and low - suva waters

Download
index.pdf
2008
Ateş, Nuray
Show full item record
188
views
142
downloads
The main objective of this study was to conduct a systematic investigation of the disinfection by-products (DBPs) formation in low-bromide and low- specific ultraviolet absorbance (SUVA) waters and the control of DBP precursors by nanofiltration (NF) and ultrafiltration (UF) processes in such waters. To this end, firstly, the effect of bromide ion on the formation and speciation of DBPs was investigated. In fractionated Alibeyköy source water, increasing bromide concentrations in NOM fractions increased concentrations of trihalomethanes (THMs), haloacetic acids (HAAs) and adsorbable organic halides (AOX) and resulted in a shift toward the formation of brominated species. Secondly, the impacts of SUVA and differential UV spectroscopy (ΔUV), which has been shown to correlate well with DBP formation has been elucidated in terms of DBP formation and speciation. Alibeyköy and Karacaören waters were fractionated employing various separation methods and it has been shown that SUVA did not correlate well with the formation and speciation of THMs and HAAs in tested low-SUVA waters. Similarly, no correlations were found among THMs/HAAs formations and ΔUV. Finally, the NOM rejection performances of NF and UF membranes were investigated. NF and UF membranes (<2000 dalton) was found to be suitable for the removal NOM from surface waters having low SUVA and low bromide contents. While higher molecular weight (HMW) fraction was successfully rejected (> 90%) by all membrane types, lower molecular weight (LMW) fraction could be removed with ranging efficiencies from 1.5 to 30%. NF membranes provided DOC, UV254 absorbance, THM, and HAA reductions up to 90%.
Environmental engineering., Water pollution
http://etd.lib.metu.edu.tr/upload/12609489/index.pdf
https://hdl.handle.net/11511/17991
Graduate School of Natural and Applied Sciences, Thesis

Suggestions

Aerobic biological treatment of opium alkaloid wastewater-effect of gamma radiation and fenton's oxidation as pretreatment
Bural, Cavit Burak; Dilek, Filiz Bengü; Department of Environmental Engineering (2008)
In this study, aerobic biological treatment of opium alkaloid wastewater and the effect of gamma preirradiation and fenton’s oxidation were investigated. First, the biodegradability of alkaloid wastewater was investigated by batch reactors and wastewater was found to be highly biodegradable providing 83 90 % COD degradation. In order to evaluate the effect of irradiation, original wastewater and irradiated wastewaters (40 & 140 kGy) were compared by means of BOD5/COD values and through aerobic batch experi...
Anaerobic treatment of opium alkaloid wastewater and effect of gamma-rays on anaerobic treatment
Özdemir, Recep Tuğrul; Dilek, Filiz Bengü; Department of Environmental Engineering (2006)
In this study, anaerobic treatability of opium alkaloid wastewater and the effect of radiation pretreatment (gamma-rays) on anaerobic treatability were investigated. Biochemical Methane Potential (BMP) assay was performed with alkaloid wastewater having initial COD values of 2400, 6000 and 9600 mg/L with and without basal medium (BM). The highest anaerobic treatment efficiency of 77% was obtained in the BMP reactor containing alkaloid wastewater with initial COD of 9600 mg/L and BM. Co-substrate use was inv...
Effect of Anaerobic Azo Dye Reduction on Continuous Sludge Digestion
Ozkan-Yucel, Umay Gokce; Gökçay, Celal Ferdi (Wiley, 2014-10-01)
Effect of continuous feeding of a reactive azo dye, reactive orange 107, and its hydrolyzed form (HRO107), on a conventional anaerobic digester was investigated in this study together with observation of change in microbial community. Laboratory-scale digesters were fed with waste activated sludge and azo dye for 575 days continuously. The influent concentrations of reactive azo dye were between 200 and 3200 mg/L. The digester performance was not adversely affected by azo dye and its reduction metabolites t...
Modeling biogeochemical dynamics in porous media: Practical considerations of pore scale variability, reaction networks, and microbial population dynamics in a sandy aquifer
King, E. L.; Tuncay, Kağan; Ortoleva, P.; Meile, C. (Elsevier BV, 2010-03-01)
Prediction of the fate and environmental impacts of groundwater contaminants requires the identification of relevant biogeochemical processes and necessitates the macroscopic representation of microbial activity occurring at the microscale. Using a well-studied sandy aquifer environment, we evaluate the importance of pore distribution on organic matter respiration in a porous medium environment by performing spatially explicit simulations of microbial metabolism at the sub-millimeter scale. Model results us...
Modification of a Conventional Anaerobic Digester for Improving the Effluent and Sludge Characteristics
Uludag-Demirer, S.; Demirer, Göksel Niyazi; Othman, M. (Wiley, 2009-12-01)
The aim of this study was to enrich the composition of anaerobic digester sludge in terms of nitrogen and phosphorus by struvite (MgNH4PO4) formation. Waste activated sludge was anaerobically digested in batch reactors under the conditions that the minimum stoichiometric requirement for struvite formation was satisfied in all reactors. For this purpose, different amounts of magnesium (Mg2+) and phosphate (PO43-) ions were added initially to the batch reactors. The results showed the effects of adding Mg2+ a...
Citation Formats
N. Ateş, “Disinfection by-products formation in low - bromide and low - suva waters,” Ph.D. - Doctoral Program, Middle East Technical University, 2008.
METU IIS - Integrated Information Service open@metu.edu.tr