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Novel donor-acceptor type green polymer bearing pyrrole as the donor unit with excellent switching times and very low band gap and its multichromic copolymers
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2009
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Çelebi, Selin
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A new neutral state green polymer, poly (2,3-bis(4-tert-butylphenyl)-5,8-di(1H-pyrrol-2-yl) quinoxaline) (PTBPPQ) was synthesized and its copolymer with bis(3,4-ethylenedioxythiophene) (BiEDOT) and 4,7-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-dodecyl-2H-benzo [1,2,3] triazole (BEBT) were produced. Finally polymers’ potential use as an electrochromic material was investigated. Electrochromic properties of the polymers were investigated by several methods including spectroelectrochemistry, kinetic and colorimetry studies. Key properties of conjugated polymers such as band gap, maximum absorption wavelength, the intergap states that appear upon doping and evolution of polaron and bipolaron bands were investigated via spectroelectrochemistry experiments. Switching times and optical contrasts of the homopolymer and the copolymer were evaluated via kinetic studies. Copolymer of TBPPQ with BiEDOT and BEBT were electrochemically synthesized and characterized. Resulting copolymer films have distinct electrochromic properties and revealed multichromism through the entire visible region. Although BiEDOT and BEBT have different oxidation potentials, the resulting copolymers have very similar redox behaviors. In a monomer free solution, both copolymers show four colors from purple, gray, light green to transmissive blue with the variation of the applied potential. Copolymerization with BiEDOT and BEBT not only decreases the band gap, Eg, but also enhances the electrochromic and optical properties. Hence, electrochemical copolymerization is considered to be a powerful tool to improve the electrochromic properties of quinoxaline derivatives. It should be noted that PTBPPQ is one of the few examples of neutral state green polymeric materials with superior switching properties. Hence, PTBPPQ can be used as a green polymeric material for display technologies.
Subject Keywords
Chemistry.
,
Electrochemistry.
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http://etd.lib.metu.edu.tr/upload/12610904/index.pdf
https://hdl.handle.net/11511/19013
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Graduate School of Natural and Applied Sciences, Thesis
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Donor acceptor type neutral state green polymer bearing pyrrole as the donor unit
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A new neutral state green polymer, poly (2,3-bis(4-tert-butylphenyl)-5,8-di(1H-pyrrol-2-yl) quinoxaline) (PTBPPQ) was synthesized and its potential use as an electrochromic material was investigated. Spectroelectrochemistry studies showed that polymer reveals two distinct absorption bands as expected for a donor-acceptor type polymer, at 408 and 745 nm. In addition, polymer has excellent switching properties with satisfactory optical contrasts and very short switching times. Outstanding optical contrast in ...
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S. Çelebi, “Novel donor-acceptor type green polymer bearing pyrrole as the donor unit with excellent switching times and very low band gap and its multichromic copolymers,” M.S. - Master of Science, Middle East Technical University, 2009.
