Electrochemical polymerization of furan and 2-methylfuran

Date

1999-02-26

Author

Demirboga, B
Önal, Ahmet Muhtar

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Conductive polyfuran and poly(2-methyl)furan are prepared by controlled potential electrolysis in acetonitrile at room temperature. It is found that conductivity of polyfuran decreased by factor of 4 when methyl group is present in the a position. Temperature effect on the rate of polymerization of furan is studied by cyclic voltammetry technique and an increase in the initial rate of polymerization was observed with increasing temperature. Apparent activation energy of electrochemical polymerization of furan was found to be 7.5 kJ/mole. The mechanism of electrochemical polymerization was investigated by in situ ESR. (C) 1999 Elsevier Science S.A. All rights reserved.

Subject Keywords

Electrochemical polymerization, Conducting polymers, Cyclic voltammetry , Polyfuran , Poly(2-methylfuran)

URI

https://hdl.handle.net/11511/33185

Collections

Department of Chemistry, Article