An Approach to the Modeling of Physical Ageing in Rubbery Polymers

Date

2006-03-29

Author

Dal, Hüsnü

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The oxidation reactions responsible for physical ageing are thermally activated processes and yield cross-linking similar to the vulcanization process and chain-scission reactions. Chain scission, is responsible for the relaxation behaviour under constant stretch, whereas cross-linking is responsible for hardening of the material. The decrease in the stretch at break upon cross-linking motivates the so called network alteration proposed in this contribution.

URI

https://hdl.handle.net/11511/34288

DOI

https://doi.org/10.1002/pamm.200610163

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Department of Mechanical Engineering, Conference / Seminar

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Citation Formats

H. Dal, “An Approach to the Modeling of Physical Ageing in Rubbery Polymers,” 2006, vol. 6, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/34288.