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Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate
Date
2004-08-01
Author
Guner, Y
Toppare, Levent Kamil
Hepuzer, Y
Yagci, Y
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).
Subject Keywords
Electrochemical polymerization
,
Conducting copolymers
,
Graft copolymers
URI
https://hdl.handle.net/11511/34604
Journal
EUROPEAN POLYMER JOURNAL
DOI
https://doi.org/10.1016/j.eurpolmj.2004.03.029
Collections
Department of Chemistry, Article