Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
A New Amperometric Alcohol Oxidase Biosensor Based on Conducting Polymer of (4,7-Dithien-2-yl-2, 1,3-benzothiadiazole)
Date
2012-01-01
Author
Tanriverdi, Simla
Tuncagil, Sevinc
Toppare, Levent Kamil
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
186
views
0
downloads
Cite This
Amperometric biosensors based on alcohol oxidase (AOX) immobilized on the conducting polymers of 3,4-ethylenedioxythiophene (PEDOT) and 4,7-dithien-2-yl-2,1,3-benzothiadiazole (TBTD) were constructed. Proposed biosensors were characterized using ethanol as the substrate and the responses were measured. Kinetic parameters, I-max, K-m and sensitivity were determined for the biosensors with or without TBTD. Optimization studies for TBTD thickness, PEDOT amount and pH were carried out. The biosensing capacity was discussed for TBTD matrix.
Subject Keywords
Materials Chemistry
,
General Chemistry
,
Polymers and Plastics
,
Ceramics and Composites
URI
https://hdl.handle.net/11511/35398
Journal
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
DOI
https://doi.org/10.1080/10601325.2012.649210
Collections
Department of Chemistry, Article
Suggestions
OpenMETU
Core
A thiazolothiazole containing multichromic polymer for glucose detection
Soylemez, S.; Kaya, H. Z.; Udum, Y. A.; Toppare, Levent Kamil (Department of Polymer Engineering, Scientific Society of Mechanical Engineering, 2019-10-01)
Donor-acceptor (DA) type monomers namely 2,5-di(thiophen-2-yl)thiazolo[5,4-d]thiazole (TTzTh) and 2,5-bis(3-methylthiophen-2-yl)thiazolo[5,4-d]thiazole (TTzMTh) were synthesized and their electrochemical and optoelectronic properties were investigated in detail. The spectro-electrochemical analysis showed that the alkyl chain substitution results in a shift in the onset of the pi-pi* transition towards longer wavelengths. Depending on the donor substituents, the polymers exhibited optical band gaps 1.65 and...
A novel multi-electrochromic polymer based on selenophene and benzotriazole via electrochemical and chemical polymerization
Demir, Fatma; Keles, Duygu; Karabag, Aliekber; Çırpan, Ali; Toppare, Levent Kamil (Informa UK Limited, 2019-03-04)
In this study, a novel donor-acceptor type monomer was designed based on selenophene and benzotriazole with a bulky pendant group and synthesized through Stille coupling reaction. The monomer was polymerized electrochemically by using cyclic voltammetry and also chemically by oxidation in the presence of FeCl3. Both polymers were then compared in terms of their optical properties, electrochemical and spectroelectrochemical behaviors, kinetic and colorimetric properties and surface morphologies. Independent ...
Contribution of Nanoclays to the Performance of Traditional Flame Retardants in ABS
Ozkaraca, Ayse Cagil; Kaynak, Cevdet (Wiley, 2012-03-01)
The purpose of this study was to investigate contribution of nanoclays to the flame retardancy performance of a traditional brominated flame retardant compound with various combinations of antimony trioxide and zinc borate. The matrix polymer acrylonitrile butadiene styrene (ABS) was compounded by melt mixing in a laboratory size twin-screw extruder. X-ray diffraction analysis and transmission electron microscopy revealed that nanoclay silicate layers were mainly intercalated with certain level of exfoliati...
Characterization and potential applications of immobilized glucose oxidase and polyphenol oxidase
Ekinci, Olcun; Boyukbayram, A. Elif; Kiralp, Senem; Toppare, Levent Kamil; Yagci, Yusuf (Informa UK Limited, 2007-07-01)
Pyrrole functionalized polystyrene (PStPy) was copolymerized with pyrrole to obtain a conducting copolymer, P(PStPy-co-Py) which is used as the immobilization matrix. Glucose oxidase and polyphenol oxidase enzymes were immobilized via the entrapment method by electrochemical polymerization. Enzyme electrodes were prepared by electrolysis at a constant potential using sodium dodecyl sulfate (SDS) as the supporting electrolyte during the copolymerization of PStPy with pyrrole. Maximum reaction rates (V-max) a...
A new donor-acceptor type polymeric material from a thiophene derivative and its electrochromic properties
Udum, Yasemin Arslan; Yildiz, Ersin; Günbaş, Emrullah Görkem; Toppare, Levent Kamil (Wiley, 2008-06-01)
A new electrochromic polymer, poly(2,3,5,8-tetra(thiophen-2-yl)quinoxaline) (PTTQ), was synthesized electrochemically and its electrochromic properties were investigated. The polymer was characterized by Cyclic Voltammetry, Fourier Transform infrared spectroscopy, LTV-Vis-NIR Spectroscopy, and colorimetry. Spectroelectrochemistry analysis demonstrated that the polymer can undergo both p- and true n-type doping processes. The polymer, (PTTQ), has three accessible color states: an oxidized transmissive, a neu...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
S. Tanriverdi, S. Tuncagil, and L. K. Toppare, “A New Amperometric Alcohol Oxidase Biosensor Based on Conducting Polymer of (4,7-Dithien-2-yl-2, 1,3-benzothiadiazole),”
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
, pp. 185–190, 2012, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35398.