Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
ELECTROINITIATED POLYMERIZATION OF BIS(TRICHLOROPHENOXO)-TETRAMETHYLETHYLENE DIAMINE COPPER(II)
Date
1989-04-01
Author
SACAK, M
Akbulut, Ural
KISAKUREK, D
TURKER, L
Toppare, Levent Kamil
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
72
views
0
downloads
Cite This
Electroninitiated polymerization of bis(trichlorophenoxo)‐N,N,N′,N′‐tetramethylethylene diamine copper(II) was achieved in acetonitrile at various peak potentials of the monomer. A constant potential approach was selected in polymerization reactions. Electrolyses were carried out under air, nitrogen, and oxygen atmospheres. Structural analyses of the polymers were done by 1H‐NMR and 13C‐NMR FT–IR spectroscopy. Molecular weights of the polymers were determined by vapor pressure (isopiestic) method.
Subject Keywords
Organic Chemistry
,
Materials Chemistry
,
Polymers and Plastics
URI
https://hdl.handle.net/11511/35993
Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
DOI
https://doi.org/10.1002/pola.1989.080270511
Collections
Department of Chemistry, Article
Suggestions
OpenMETU
Core
POLYMERIZATION OF BIS(TRICHLOROPHENOXO) ETHYLENEDIAMINE COPPER (II) COMPLEX BY ELECTRO-OXIDATION
Yiğit, S.; Kısakürek, D.; Türker, L; Toppare, Levent Kamil; Akbulut, Ural (Elsevier BV, 1989-02-01)
Electroinitiated polymerization of bis(trichlorophenoxo) ethylenediamine copper (II) complex was carried out in dimethyl-formamide at various anodic peak potentials of the complex. The oxidation and reduction peak potentials were determined by cyclic voltammetry. These potentials were measured in tetrabutylammonium fluoroborate-dimethylformamide supporting electrolyte-solvent couple at room temperature. Polymerization reactions were carried out under air and nitrogen atmospheres using a constant potential a...
SYNTHESIS AND CHARACTERIZATION OF POLY(DICHLOROPHENYLENE OXIDE)S THROUGH SOLID-STATE THERMAL-DECOMPOSITION OF BIS(PYRIDINE)BIS(TRICHLOROPHENOXO)COPPER(II) COMPLEXES
BASTURKMEN, M; KISAKUREK, D (Elsevier BV, 1993-01-01)
Thermal polymerization of bis(pyridine)bis(trichlorophenoxo)copper(II) was achieved in the solid state for the first time. The time and temperature effect on polymer molecular weight, percentage yield and the structure of polymer was first studied, at constant temperature and then for constant decomposition time. Polymers were characterized by i.r., H-1 n.m.r. and C-13 n.m.r. The molecular weights of the polymers were obtained by viscometric measurements at 30-degrees-C in toluene and glass transition tempe...
POLYMERIZATION OF BIS(PYRIDINE)BIS-(2,4,6-TRIBROMOPHENOXO)COPPER(II) COMPLEX (PY2CU(TBRP)2) BY ELECTROOXIDATION AND STRUCTURAL CHARACTERIZATION BY H-1-NMR, C-13-NMR, AND FTIR SPECTROSCOPIES
SEN, S; KISAKUREK, D; Toppare, Levent Kamil (Informa UK Limited, 1993-01-01)
Electroinitiated polymerization of bis(2,4,6-tribromophenoxo)-bis(pyridine)copper(II) complex was achieved in dimethylformamide-tetrabutylammonium tetrafluoroborate solvent-electrolyte couple under air or nitrogen at room temperature by constant potential electrolysis. Polymerization conditions were based on the peak potentials measured by cyclic voltammetry. The structural analyses of the polymers were done by H-1-NMR, C-13-NMR, and FTIR spectral analyses along with molecular weight measurements by cryosco...
Thermal polymerization of bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex in solution and in solid state
Kisakurek, D; Akbas, M; Bilir, N (Wiley, 1998-02-01)
The synthesis of the bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex was achieved from aqueous solution, and its characterization was performed by means-of IR and CHN elemental analysis. Thermal polymerization of this complex was carried out in toluene and in solid state. The structural analysis of the polymers was performed with H-1 NMR, C-13 NMR and FTIR analysis; the glass transition temperature was found to be at 160 degrees C. 4-Fluoro-2,6-dibromophenolate, with the non-chelating liga...
POLYMERIZATION OF BIS(2-BROMO-4,6-DICHLOROPHENOXO)BIS(PYRIDINE) COPPER (II) COMPLEX IN DMF BY ELECTROINITIATION
KISAKUREK, D; SEN, S; ARAS, L; TURKER, L; Toppare, Levent Kamil (Elsevier BV, 1991-01-01)
Polymerization of bis(2-bromo-4,6-dichlorophenoxo)bis(pyridine) copper (II) complex was achieved in dimethylformamide by electrooxidation. A cyclic voltammogram (CV) of the complex was obtained in dimethylformamide in advance. Constant potential yielded polymers in anode compartment only under nitrogen atmosphere and air. In the final polymer product, incorporation of neither the ligand nor the copper was observed and the post-polymerization proceeded in the absence of current. The structural analyses o...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
M. SACAK, U. Akbulut, D. KISAKUREK, L. TURKER, and L. K. Toppare, “ELECTROINITIATED POLYMERIZATION OF BIS(TRICHLOROPHENOXO)-TETRAMETHYLETHYLENE DIAMINE COPPER(II),”
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
, pp. 1599–1608, 1989, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35993.