CHARACTERIZATION OF ELECTROINITIATED AND RADIATION POLYMERIZED POLY(BUTADIENE SULFONE)

Date

1991-01-01

Author

HACIOGLU, B
SUZER, S
Akbulut, Ural
Toppare, Levent Kamil
AYBAR, P
UTLEY, JHP

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Polymerization of butadiene sulfone was accomplished by using two different methods. The first method involves electrochemical polymerization of the monomer using the constant potential electrolysis technique. Oxidation of the monomer under nitrogen atmosphere in an acetonitrile-tetrabutylammonium tetrafluoroborate system yields brown, tarry polymers. On the other hand, the second initiation method, which was radiation polymerization, yields white, powdery polymers. Structural analyses of the two polymers by various spectroscopic methods suggest a structure consisting of two different units in different proportions.

Subject Keywords

General Engineering

URI

https://hdl.handle.net/11511/36016

Journal

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY

DOI

https://doi.org/10.1080/00222339108052146

Collections

Department of Chemistry, Article

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Citation Formats

B. HACIOGLU, S. SUZER, U. Akbulut, L. K. Toppare, P. AYBAR, and J. UTLEY, “CHARACTERIZATION OF ELECTROINITIATED AND RADIATION POLYMERIZED POLY(BUTADIENE SULFONE),” JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, pp. 329–345, 1991, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36016.