Electrochromic properties of a soluble conducting polymer: Poly(1-(4-fluorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole)

Date

2007-08-15

Author

ARSLAN, Ahu
Tuerkarslan, Oezlem
Tanyeli, Cihangir
Akhmedov, Idris Mecidoglu
Toppare, Levent Kamil

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1-(4-Fluorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole (FPTP) was synthesized and polymerized both chemically and electrochemically. Spectroelectrochemistry experiments reflected a pi to pi* transition with a band gap energy of 1.94eV for the polymer. A dual type electrochromic device (ECD) of P(FPTP) and poly(3,4-ethylenedioxythiophene) (PEDOT) was constructed. The device switches between yellow and blue upon application of -0.8 V and +1.1 V, respectively. Optical contrast was calculated as 19.4% whereas switching time was found as 1.4s at maximum contrast point. (c) 2007 Elsevier B.V.. All rights reserved.

Subject Keywords

General Materials Science, Condensed Matter Physics

URI

https://hdl.handle.net/11511/36224

Journal

MATERIALS CHEMISTRY AND PHYSICS

DOI

https://doi.org/10.1016/j.matchemphys.2007.03.035

Collections

Department of Chemistry, Article

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Citation Formats

A. ARSLAN, O. Tuerkarslan, C. Tanyeli, I. M. Akhmedov, and L. K. Toppare, “Electrochromic properties of a soluble conducting polymer: Poly(1-(4-fluorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole),” MATERIALS CHEMISTRY AND PHYSICS, pp. 410–416, 2007, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36224.