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Conducting polymers of decanedioic acid bis-(4-pyrrol-1-yl-phenyl) ester
Date
2004-05-15
Author
Çırpan, Ali
Toppare, Levent Kamil
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A dipyrrolyl monomer was synthesized via the reaction between 4-pyrrol-1-yl phenol and decanedioyl dichloride. The electrochemical behavior of this monomer was studied. Polymerization of decanedioic acid bis-(4-pyrrol-1-yi-phenyl) ester (DAPE) was achieved by chemical and constant current electrolyses methods. Copolymerization of DAPE with thiophene was performed by constant potential electrolysis in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), dichloromethane-TBAFB, solvent-electrolyte couples. The chemical structures and properties were investigated by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, differential scanning calorimetry and thermal gravimetry analysis. The conductivities of the samples were measured by a four-probe technique.
Subject Keywords
General Materials Science
,
Condensed Matter Physics
URI
https://hdl.handle.net/11511/44441
Journal
MATERIALS CHEMISTRY AND PHYSICS
DOI
https://doi.org/10.1016/j.matchemphys.2004.01.014
Collections
Department of Chemistry, Article
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A. Çırpan and L. K. Toppare, “Conducting polymers of decanedioic acid bis-(4-pyrrol-1-yl-phenyl) ester,”
MATERIALS CHEMISTRY AND PHYSICS
, pp. 222–226, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/44441.