Conducting polymers of decanedioic acid bis-(4-pyrrol-1-yl-phenyl) ester

Date

2004-05-15

Author

Çırpan, Ali
Toppare, Levent Kamil

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A dipyrrolyl monomer was synthesized via the reaction between 4-pyrrol-1-yl phenol and decanedioyl dichloride. The electrochemical behavior of this monomer was studied. Polymerization of decanedioic acid bis-(4-pyrrol-1-yi-phenyl) ester (DAPE) was achieved by chemical and constant current electrolyses methods. Copolymerization of DAPE with thiophene was performed by constant potential electrolysis in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), dichloromethane-TBAFB, solvent-electrolyte couples. The chemical structures and properties were investigated by Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, differential scanning calorimetry and thermal gravimetry analysis. The conductivities of the samples were measured by a four-probe technique.

Subject Keywords

General Materials Science, Condensed Matter Physics

URI

https://hdl.handle.net/11511/44441

Journal

MATERIALS CHEMISTRY AND PHYSICS

DOI

https://doi.org/10.1016/j.matchemphys.2004.01.014

Collections

Department of Chemistry, Article

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Citation Formats

A. Çırpan and L. K. Toppare, “Conducting polymers of decanedioic acid bis-(4-pyrrol-1-yl-phenyl) ester,” MATERIALS CHEMISTRY AND PHYSICS, pp. 222–226, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/44441.