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Enantioselective direct aldol reactions promoted by phosphine oxide aziridinyl phosphonate organocatalysts
Date
2015-12-15
Author
Doğan, Özdemir
Metadata
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A series of phosphine oxide based chiral Lewis bases were screened as organocatalysts for silicon tetrachloride mediated direct asymmetric aldol reactions between cyclohexanone and various aromatic aldehydes. One of the phosphine oxide-aziridinyl phosphonate POAP-A Lewis bases formed the aldol products in up to 75% yield and with 65% ee.
Subject Keywords
Lewis-Base Catalyst
,
Asymmetric Allylation
,
Highly Efficient
,
Aldehydes
,
Epoxides
,
Additions
,
Silicon
,
Ligand
,
Binapo
URI
https://hdl.handle.net/11511/36492
Journal
TETRAHEDRON-ASYMMETRY
DOI
https://doi.org/10.1016/j.tetasy.2015.10.013
Collections
Department of Chemistry, Article
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Ö. Doğan, “Enantioselective direct aldol reactions promoted by phosphine oxide aziridinyl phosphonate organocatalysts,”
TETRAHEDRON-ASYMMETRY
, pp. 1348–1353, 2015, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36492.